Branched-Selective Decarboxylative Heck Reaction with Electronically Unbiased Olefins - Details

author：

Shen, J. (Shen, J..) ^[1] | Xu, B. (Xu, B..) ^[2] | Zhang, M. (Zhang, M..) ^[3] | Su, W. (Su, W..) ^[4]

Indexed by：

Scopus

Abstract：

We　describe　the　PdII-catalyzed　decarboxylative　Heck　reaction　of　aromatic　carboxylic　acids　with　an　array　of　electronically　unbiased　olefins,　which　allows　regioselective　formation　of　less　common　branched　products　in　good　yield.　This　protocol　enables　the　use　of　inexpensive,　stable,　and　readily　available　aromatic　carboxylic　acids　as　aryl　reagents,　thus　providing　an　attractive　method　for　the　synthesis　of　useful　α-alkyl　vinylarenes.　©　2018　WILEY-VCH　Verlag　GmbH　&　Co.　KGaA,　Weinheim

Keyword：

Decarboxylation; Heck reaction; Homogeneous catalysis; Olefins; Regioselectivity

Community：

[ 1 ] [Shen, J.]College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 2 ] [Shen, J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155, Fuzhou, Fujian 350002, China
[ 3 ] [Xu, B.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155, Fuzhou, Fujian 350002, China
[ 4 ] [Zhang, M.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155, Fuzhou, Fujian 350002, China
[ 5 ] [Su, W.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Zhang, M.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Yangqiao West Road 155, China

Email：

zhangmin@fjirsm.ac.cn

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Source ：

European Journal of Organic Chemistry

ISSN： 1434-193X

Year： 2018

Issue： 22

Volume： 2018

Page： 2768-2773

3 . 0 2 9

JCR@2018

2 . 5 0 0

JCR@2023

ESI HC Threshold：209

JCR Journal Grade：2

CAS Journal Grade：3

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 6

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 0

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