A rare porous zinc phosphonocarboxylate framework with high thermal stability and interesting structural transformation - Details

author：

Qi, Y.-J. (Qi, Y.-J..) ^[1] | Liu, J.-H. (Liu, J.-H..) ^[2] | Zheng, W.-X. (Zheng, W.-X..) ^[3] | Li, X.-X. (Li, X.-X..) ^[4] | Zheng, S.-T. (Zheng, S.-T..) ^[5]

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Abstract：

A　rare　porous　zinc-organic　framework　with　ultrahigh　thermal　stability　over　500　°C　was　obtained,　which　exhibits　a　CaF2-type　topology　formed　by　8-connected　tetranuclear　Zn4　clusters　and　4-connected　phosphonocarboxylate　ligands.　Interestingly,　the　similar　reactions　to　the　zinc-organic　framework　but　in　the　absence　of　H2O　or　by　the　replacement　of　Zn2+　with　Co2+　can　yield　three　different　3D　cluster-based　frameworks　but　with　the　same　CaF2-type　topology.　©　2018　The　Author

Keyword：

Gas adsorption; Metal-organic framework; Phosphonocarboxylate ligand; Stability; Structural transformation

Community：

[ 1 ] [Qi, Y.-J.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Liu, J.-H.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 3 ] [Zheng, W.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 4 ] [Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 5 ] [Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350108, China

Reprint 's Address：

[Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

Email：

stzheng@fzu.edu.cn

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Source ：

Chinese Chemical Letters

ISSN： 1001-8417

Year： 2018

Issue： 6

Volume： 29

Page： 959-962

3 . 8 3 9

JCR@2018

9 . 4 0 0

JCR@2023

ESI HC Threshold：209

JCR Journal Grade：2

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

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