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author:

Qiu, M. (Qiu, M..) [1] | Tao, H.-L. (Tao, H.-L..) [2] | Li, Y. (Li, Y..) [3] | Huang, X. (Huang, X..) [4] | Zhang, Y.-F. (Zhang, Y.-F..) [5]

Indexed by:

Scopus CSCD

Abstract:

Periodic density functional theory calculations have been carried out to investigate the effect of TM atom supported on different Cusurfaces towards the activation for CO2molecules. The most stable configuration of CO2on various TM/Cu (TM = Fe, Co, Ni, Cu) surfaces is determined and the results show that the cobalt is potentially excellent admetal to enhance the chemisorption of CO2on copper surfaces among the late 3d-metals. To deep understand the adsorption property, the bondcharacteristics of the adsorption bonds are carefully examined by the crystal orbital Hamilton population technique and charge density difference analysis. The result reveals that the interaction between the CO2molecule and TM/Cu surface primarily derive from the TM-Cbond. Moreover, the defined adsorption bond strength(I) between CO2and substrate could be a descriptor for TM-supported surface. © 2018 Fujian Institute of Research of the Structure of Matter. All rights reserved.

Keyword:

Carbon dioxide; Chemisorption; DFT; Transition metal surfaces

Community:

  • [ 1 ] [Qiu, M.]College of Science, Jiangxi AgriculturalUniversity, Nanchang, Jiangxi, 330045, China
  • [ 2 ] [Tao, H.-L.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 3 ] [Li, Y.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Huang, X.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [Zhang, Y.-F.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address:

  • [Qiu, M.]College of Science, Jiangxi AgriculturalUniversityChina

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Source :

Jiegou Huaxue

ISSN: 0254-5861

CN: 35-1112/TQ

Year: 2018

Issue: 5

Volume: 37

Page: 665-678

0 . 6 9 5

JCR@2018

5 . 9 0 0

JCR@2023

ESI HC Threshold:209

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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