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Abstract:
Periodic density functional theory calculations have been carried out to investigate the effect of TM atom supported on different Cusurfaces towards the activation for CO2molecules. The most stable configuration of CO2on various TM/Cu (TM = Fe, Co, Ni, Cu) surfaces is determined and the results show that the cobalt is potentially excellent admetal to enhance the chemisorption of CO2on copper surfaces among the late 3d-metals. To deep understand the adsorption property, the bondcharacteristics of the adsorption bonds are carefully examined by the crystal orbital Hamilton population technique and charge density difference analysis. The result reveals that the interaction between the CO2molecule and TM/Cu surface primarily derive from the TM-Cbond. Moreover, the defined adsorption bond strength(I) between CO2and substrate could be a descriptor for TM-supported surface. © 2018 Fujian Institute of Research of the Structure of Matter. All rights reserved.
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Jiegou Huaxue
ISSN: 0254-5861
CN: 35-1112/TQ
Year: 2018
Issue: 5
Volume: 37
Page: 665-678
0 . 6 9 5
JCR@2018
5 . 9 0 0
JCR@2023
ESI HC Threshold:209
JCR Journal Grade:4
CAS Journal Grade:4
Cited Count:
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 2
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