• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Zhang, Y. (Zhang, Y..) [1] | Li, Q. (Li, Q..) [2] | Liu, C. (Liu, C..) [3] | Shan, X. (Shan, X..) [4] | Chen, X. (Chen, X..) [5] | Dai, W. (Dai, W..) [6] | Fu, X. (Fu, X..) [7]

Indexed by:

Scopus

Abstract:

A gold nanoparticle catalyst supported on the ZIF-8 (a metal-organic frameworks) modified TiO2 (Au/ZIF-8-TiO2) was prepared by self-assembly together with solvothermal and deposition-precipitation methods, which its performance of catalytic oxidizing CO was evaluated and compared with that of Au/TiO2 and Au/ZIF-8, respectively. It was found that the incorporation of ZIF-8 into Au/TiO2 could remarkably enhance the catalytic activity of Au/TiO2 both in dark and under visible light irradiation. The characterization result of Au/ZIF-8-TiO2 showed that the sheet of ZIF-8 was distributed on the surface of TiO2 microspheres to enhance the surface roughness of TiO2, which could effectively limit the migration and aggregation of Au nanoparticles (i.e., enhancing the dispersion of Au nanoparticles at support) due to its large surface area and porousness. Moreover, Au/ZIF-8-TiO2 owned a higher surface electron density of both Au nanoparticles and TiO2 as compared to Au/TiO2. It is proposed that ZIF-8 with abundant delocalized electrons of π bond could act as an electron donor for TiO2 and Au in the structure of Au/ZIF-8-TiO2, but it act as an electron transfer mediator to promote the electron transfer between Au and TiO2 induced by the localized surface plasmon resonance of Au nanoparticles under visible light irradiation. These behaviors would promote the adsorption and activation of CO and O2 at Au or TiO2 sites, resulting in the enhanced CO oxidation. © 2017 Elsevier B.V.

Keyword:

Electron transfer; Localized surface plasmon resonance of Au nanoparticles; Metal-organic frameworks; Oxidation of carbon monoxide; TiO2 supported Au catalyst

Community:

  • [ 1 ] [Zhang, Y.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China
  • [ 2 ] [Zhang, Y.]Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, Fuzhou, 350002, China
  • [ 3 ] [Li, Q.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China
  • [ 4 ] [Li, Q.]Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, Fuzhou, 350002, China
  • [ 5 ] [Liu, C.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China
  • [ 6 ] [Liu, C.]Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, Fuzhou, 350002, China
  • [ 7 ] [Shan, X.]Zhejiang Harmony Photocatalytic Technology Co., Ltd, Shaoxing, 312366, China
  • [ 8 ] [Chen, X.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China
  • [ 9 ] [Dai, W.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China
  • [ 10 ] [Dai, W.]Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, Fuzhou, 350002, China
  • [ 11 ] [Fu, X.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China

Reprint 's Address:

  • [Dai, W.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou UniversityChina

Show more details

Related Keywords:

Related Article:

Source :

Applied Catalysis B: Environmental

ISSN: 0926-3373

Year: 2018

Volume: 224

Page: 283-294

1 4 . 2 2 9

JCR@2018

2 0 . 3 0 0

JCR@2023

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 78

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

Affiliated Colleges:

Online/Total:186/10012374
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1