Synthesis and characterization of cyclophane: The highly selective recognition of Fe3+ in aqueous solution and H2PO4 − in acetonitrile solution - Details

author：

Zhou, J. (Zhou, J..) ^[1] | Yuan, Y.-F. (Yuan, Y.-F..) ^[2] | Zhuo, J.-B. (Zhuo, J.-B..) ^[3] | Lin, C.-X. (Lin, C.-X..) ^[4]

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Abstract：

In　this　work,　we　report　a　series　of　cyclophane　fluorescent　sensors　based　on　acridine　combining　with　imidazolium　through　ether　linkages.　X-ray　crystal　structures　demonstrated　the　self-assembly　behavior　of　these　cyclophanes　in　the　solid　state　driven　by　hydrogen　bond　and　π–π　interactions.　Sensors　showed　excellent　selectivity　towards　Fe3+　in　aqueous　solution　(H2O/CH3CN　=　49:1,　v/v)　and　H2PO4　−　in　acetonitrile　solution　with　notable　color　change　under　UV　light,　evident　changes　were　also　noticed　in　fluorescence　spectra.　In　fluorescence　emission,　the　obvious　turn-off　was　induced　by　Fe3+　in　aqueous　solution　and　the　obvious　turn-on　as　well　as　bathochromic-shift　was　induced　by　H2PO4　−　in　acetonitrile　solution.　©　2018　Elsevier　Ltd

Keyword：

Bathochromic-shift; Chemosensor; Cyclophane; Fe3+ and H2PO4 −; Hydrophilicity

Community：

[ 1 ] [Zhou, J.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, China
[ 2 ] [Yuan, Y.-F.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, China
[ 3 ] [Yuan, Y.-F.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 4 ] [Zhuo, J.-B.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, China
[ 5 ] [Zhuo, J.-B.]Fuyuan Biotechnologies Co., Ltd., Fuzhou, 350001, China
[ 6 ] [Lin, C.-X.]Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, China

Reprint 's Address：

[Yuan, Y.-F.]Department of Chemistry, Fuzhou UniversityChina

Email：

yaofeng_yuan@fzu.edu.cn

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Source ：

Tetrahedron Letters

ISSN： 0040-4039

Year： 2018

Issue： 11

Volume： 59

Page： 1059-1064

2 . 2 5 9

JCR@2018

1 . 5 0 0

JCR@2023

ESI HC Threshold：209

JCR Journal Grade：2

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count： 17

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 4

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