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author:

Wang, Z. (Wang, Z..) [1] | Cao, F. (Cao, F..) [2] | Chen, K. (Chen, K..) [3] | Yan, Y. (Yan, Y..) [4] | Chen, Y. (Chen, Y..) [5] | Zhang, Y. (Zhang, Y..) [6] | Zhu, X. (Zhu, X..) [7] | Wei, B. (Wei, B..) [8] | Xiong, Y. (Xiong, Y..) [9] | Lv, Z. (Lv, Z..) [10]

Indexed by:

Scopus

Abstract:

Cellular metals with the large surface/volume ratios and excellent electrical conductivity are widely applicable and have thus been studied extensively. It is highly desirable to develop a facile and cost-effective process for fabrication of porous metallic structures, and yet more so for micro/nanoporous structures. A direct-flame strategy is developed for in situ fabrication of micron-scale cellular architecture on a Ni metal precursor. The flame provides the required heat and also serves as a fuel reformer, which provides a gas mixture of H 2 , CO, and O 2 for redox treatment of metallic Ni. The redox processes at elevated temperatures allow fast reconstruction of the metal, leading to a cellular structure on Ni wire. This process is simple and clean and avoids the use of sacrificial materials or templates. Furthermore, nanocrystalline MnO 2 is coated on the microporous Ni wire (MPNW) to form a supercapacitor electrode. The MnO 2 /MPNW electrode and the corresponding fiber-shaped supercapacitor exhibit high specific capacitance and excellent cycling stability. Moreover, this work provides a novel strategy for the fabrication of cellular metals and alloys for a variety of applications, including catalysis, energy storage and conversion, and chemical sensing. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Keyword:

cellular architecture; energy transfer; flame; redox process; transition metal

Community:

  • [ 1 ] [Wang, Z.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin, Heilongjiang 150001, China
  • [ 2 ] [Cao, F.]School of Mechatronic Engineering, Daqing Normal University, Daqing, Heilongjiang 163712, China
  • [ 3 ] [Chen, K.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian, 350108, China
  • [ 4 ] [Yan, Y.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin, Heilongjiang 150001, China
  • [ 5 ] [Chen, Y.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin, Heilongjiang 150001, China
  • [ 6 ] [Zhang, Y.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin, Heilongjiang 150001, China
  • [ 7 ] [Zhu, X.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin, Heilongjiang 150001, China
  • [ 8 ] [Wei, B.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin, Heilongjiang 150001, China
  • [ 9 ] [Xiong, Y.]MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, 92 West Dazhi Street, Harbin, 150001, China
  • [ 10 ] [Lv, Z.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, Harbin, Heilongjiang 150001, China

Reprint 's Address:

  • [Wang, Z.]Department of Physics, Harbin Institute of Technology, Yikuang Street 2#, China

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Source :

ChemSusChem

ISSN: 1864-5631

Year: 2018

Issue: 5

Volume: 11

Page: 985-993

7 . 8 0 4

JCR@2018

7 . 5 0 0

JCR@2023

ESI HC Threshold:209

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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