Construction of Zeolite-Like Cluster Organic Frameworks from 3 d–4 d/3 d–3 d Heterometallic Supertetrahedral Secondary Building Units: Syntheses, Structures, and Properties - Details

author：

Lin, L.-D. (Lin, L.-D..) ^[1] | Deng, C.-C. (Deng, C.-C..) ^[2] | Zhao, D. (Zhao, D..) ^[3] | Li, X.-X. (Li, X.-X..) ^[4] | Zheng, S.-T. (Zheng, S.-T..) ^[5]

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Abstract：

Two　zeolite-like　cluster　organic　frameworks　based　on　Cd-Cu/Mn-Cu　heterometallic　supertetrahedral　secondary　building　units　have　been　successfully　constructed　under　solvothermal　conditions,　namely,　Cu[Cd4Cu6(L)4(H2O)18](Ac)9⋅DMA⋅3　H2O　(1),　and　Cu[Mn4Cu6(L)4(Ac)3(H2O)12](Ac)6⋅CH3CN⋅13　H2O　(2),　where　H3L=2-(hydroxymethyl)-2-(pyridin-4-yl)-1,3-propanediol,　Ac=CH3COO−,　DMA=N,N′-dimethylacetamide.　Single-crystal　X-ray　structural　analysis　reveals　that　both　1　and　2　exhibit　3-dimensional　zeolite-like　architectures　with　similar　4-connected　components,　but　possess　definitely　different　topologies　of　diamondoid　(dia)　and　uncommon　lonsdaleite　(lon),　respectively.　1　and　2　represent　the　first　cases　of　zeolite-like　cluster　organic　frameworks　containing　Cd-Cu/Mn-Cu　heterometallic　supertetrahedral　secondary　building　units.　Furthermore,　the　magnetic　properties　and　porous　nature　of　1　and　2　were　also　studied.　©　2018　Wiley-VCH　Verlag　GmbH　&　Co.　KGaA,　Weinheim

Keyword：

4-connected SBUs; cluster organic frameworks; gas absorption; magnetic properties; zeolite-like

Community：

[ 1 ] [Lin, L.-D.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 2 ] [Deng, C.-C.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 3 ] [Zhao, D.]Fuqing Branch of Fujian Normal University, Fujian, Fuqing 350300, China
[ 4 ] [Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 5 ] [Li, X.-X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 6 ] [Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
[ 7 ] [Zheng, S.-T.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Reprint 's Address：

[Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

Email：

lxx@fzu.edu.cn

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Source ：

Chemistry - A European Journal

ISSN： 0947-6539

Year： 2018

Issue： 1

Volume： 24

Page： 251-258

5 . 1 6

JCR@2018

3 . 9 0 0

JCR@2023

ESI HC Threshold：209

JCR Journal Grade：1

CAS Journal Grade：3

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WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 0

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