A lead-free perovskite-like hybrid with above-room-temperature switching of quadratic nonlinear optical properties - Details

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Abstract：

We　report　a　new　lead-free　perovskite-like　hybrid,　composed　of　hexamethyleneimine　and　one-dimensional　[SbCl5]n2-　polyanionic　zigzag　chains,　which　shows　above-room-temperature　switching　of　quadratic　nonlinear　optical　(NLO)　properties　induced　by　the　unique　order-disorder　conformational　changes　of　the　organic　cation.　©　The　Royal　Society　of　Chemistry　2018.

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[ 1 ] [Zhang, J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 2 ] [Zhang, J.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 3 ] [Han, S.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 4 ] [Liu, X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 5 ] [Wu, Z.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 6 ] [Ji, C.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 7 ] [Sun, Z.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 8 ] [Sun, Z.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 9 ] [Luo, J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China

Reprint 's Address：

[Sun, Z.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesChina

Email：

sunzhihua@fjirsm.ac.cn

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Chemical Communications

ISSN： 1359-7345

Year： 2018

Issue： 44

Volume： 54

Page： 5614-5617

6 . 1 6 4

JCR@2018

4 . 3 0 0

JCR@2023

ESI HC Threshold：209

JCR Journal Grade：1

CAS Journal Grade：2

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WoS CC Cited Count：

SCOPUS Cited Count： 40

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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