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author:

Wu, X. (Wu, X..) [1] | Lei, Y. (Lei, Y..) [2] | Li, S. (Li, S..) [3] | Huang, J. (Huang, J..) [4] | Teng, L. (Teng, L..) [5] | Chen, Z. (Chen, Z..) [6] | Lai, Y. (Lai, Y..) [7]

Indexed by:

Scopus

Abstract:

Fast and efficient cleanup of high-viscosity oil spills on the sea is still a global challenge today. Traditional recycling methods are either energy demanding or inefficient. Hydrophobic/oleophilic sorbents are promising candidates to handle oil spills, but they have limited ability to recover high viscosity oil. In this work, we report a superhydrophobic/oleophilic carbon nanotubes (CNT) and polypyrrole (PPy) coated melamine sponge (m-CNT/PPy@MS). The CNT/PPy coating enables the sponge to convert light and electricity to heat, ensuring that the absorbent can adapt to various working environments. The rapid heat generation on the sponge surface can significantly reduce the viscosity of crude oil and accelerate the absorption rate, thereby achieving the purpose of rapid recovery of oil spills. Under one sun illumination (1.0 kW/m2) and an applied voltage (8 V), the surface temperature of the m-CNT/PPy@MS can reach 118.6 °C. The complete penetration time of oil droplets is 93.5% less than that of an unheated sponge. In addition, under half sun irradiation intensity and 11 V, the porous sponge absorbed 6.92 kg/m2 of crude oil in the first minute, which is about 31 times as much as that of an unheated sponge. Finally, we demonstrate a continuous absorption system, consisting of a self-heating m-CNT/PPy@MS and peristaltic pump, that can continuously recover oil spills on the sea surface. In view of its unique design, lower cost and fast oil absorption speed, this work provides a new option to tackle large-scale oil spill disasters on the sea surface. © 2020 Elsevier B.V.

Keyword:

CNT/PPy composite coating; Crude oil spill remediation; Joule heating-assisted; Photothermal conversion; Superhydrophobic/oleophilic property

Community:

  • [ 1 ] [Wu, X.]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Lei, Y.]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 3 ] [Li, S.]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Li, S.]National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou, 215123, China
  • [ 5 ] [Huang, J.]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 6 ] [Teng, L.]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 7 ] [Chen, Z.]School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore
  • [ 8 ] [Lai, Y.]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address:

  • [Huang, J.]National Engineering Research Center of Chemical Fertilizer Catalyst (NERC-CFC), College of Chemical Engineering, Fuzhou UniversityChina

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Source :

Journal of Hazardous Materials

ISSN: 0304-3894

Year: 2021

Volume: 403

1 4 . 2 2 4

JCR@2021

1 2 . 2 0 0

JCR@2023

ESI HC Threshold:105

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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