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author:

Ding, Y. (Ding, Y..) [1] | Wei, D. (Wei, D..) [2] | He, R. (He, R..) [3] | Yuan, R. (Yuan, R..) [4] | Xie, T. (Xie, T..) [5] | Li, Z. (Li, Z..) [6]

Indexed by:

Scopus

Abstract:

ZnIn2S4/WO3 nanocomposites, with ZnIn2S4 nanosheets loaded on WO3 nanorods, were synthesized by self-assembly of hexagonal ZnIn2S4 in the presence of preformed WO3·H2O nanoplates. PtS and MnO2, the co-catalysts for H2 and O2 evolution, respectively, were selectively loaded on ZnIn2S4 and WO3 in the nanocomposites. The resultant PtS-ZnIn2S4/WO3-MnO2 nanocomposites show photocatalytic activity for overall water splitting to produce H2 and O2 under visible light. An optimum activity was achieved over 0.5%PtS-20%ZnIn2S4/WO3-3.0%MnO2, in which 5.94 μmol of H2 and 2.24 μmol O2 were evolved in 8 h. The apparent quantum yield (AQY) for H2 evolution was determined to be ca. 0.50% at 420 nm. The superior photocatalytic activity for overall water splitting over PtS-ZnIn2S4/WO3-MnO2 nanocomposites can be ascribed to an efficient coupling of photocatalytic water reduction over PtS-ZnIn2S4 and photocatalytic water oxidation over MnO2-WO3 via a Z-scheme charge transfer pathway. This study demonstrates a high potential of fabrication of the all-solid Z-scheme photocatalytic systems for overall water splitting. © 2019 Elsevier B.V.

Keyword:

co-catalyst; direct Z-scheme; overall water splitting; photocatalysis

Community:

  • [ 1 ] [Ding, Y.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Wei, D.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 3 ] [He, R.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Yuan, R.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [Xie, T.]State Key Laboratory of Theoretical and Computational Chemistry, College of Chemistry, Jilin University, Changchun, Jilin 130012, China
  • [ 6 ] [Li, Z.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address:

  • [Xie, T.]State Key Laboratory of Theoretical and Computational Chemistry, College of Chemistry, Jilin UniversityChina

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Source :

Applied Catalysis B: Environmental

ISSN: 0926-3373

Year: 2019

Volume: 258

1 6 . 6 8 3

JCR@2019

2 0 . 3 0 0

JCR@2023

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 90

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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