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author:

Sun, H. (Sun, H..) [1] | Lv, Y. (Lv, Y..) [2] | Zhu, Y. (Zhu, Y..) [3] | Lin, J. (Lin, J..) [4] | Wu, X. (Wu, X..) [5] | Zhang, Q. (Zhang, Q..) [6] | Hao, X. (Hao, X..) [7]

Indexed by:

Scopus

Abstract:

The (K0.5Na0.5)0.95Li0.05Nb0.95Bi0.05O3-1mol% Er2O3 transparent ceramics were prepared by a pressureless sintering method. The fabricated transparent ceramics not only exhibit high optical transmittance (85.3%) due to dense microstructure (nanoscale size grains), but also show the photochromism-induced light scattering and reversible upconversion (UC)-switching properties by visible light irradiation. Upon 407 nm light irradiation, the optical transmittance intensity is significantly decreased, showing a strong light scattering (ΔAbs = 28.3%). The light scatting degree can be quantitatively reflected by Er3+ ion UC emission, and could be recovered to its initial optical transmittance based on photochromic reactions. Meanwhile, the transparent ceramic is found to maintain good energy storage properties with higher W (5.87 J/cm3) and Wrec (1.96 J/cm3) under a higher electric field of 260 kV/cm. These results suggest that Er3+ doped (K0.5Na0.5)NbO3 transparent ceramics are promising for the modulation of light scattering and the design of photoelectric multifunction devices. © 2019 The American Ceramic Society

Keyword:

energy storage properties; lead-free transparent ceramics; light scattering; photochromic behavior; upconversion emission

Community:

  • [ 1 ] [Sun, H.]Inner Mongolia Key Laboratory of Ferroelectric-related New Energy Materials and Devices, School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, China
  • [ 2 ] [Lv, Y.]Inner Mongolia Key Laboratory of Ferroelectric-related New Energy Materials and Devices, School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, China
  • [ 3 ] [Zhu, Y.]Inner Mongolia Key Laboratory of Ferroelectric-related New Energy Materials and Devices, School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, China
  • [ 4 ] [Lin, J.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, China
  • [ 5 ] [Wu, X.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, China
  • [ 6 ] [Zhang, Q.]Inner Mongolia Key Laboratory of Ferroelectric-related New Energy Materials and Devices, School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, China
  • [ 7 ] [Zhang, Q.]Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou, China
  • [ 8 ] [Hao, X.]Inner Mongolia Key Laboratory of Ferroelectric-related New Energy Materials and Devices, School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou, China
  • [ 9 ] [Hao, X.]Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou, China

Reprint 's Address:

  • [Wu, X.]College of Materials Science and Engineering, Fuzhou UniversityChina

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Source :

Journal of the American Ceramic Society

ISSN: 0002-7820

Year: 2019

Issue: 11

Volume: 102

Page: 6732-6740

3 . 5 0 2

JCR@2019

3 . 5 0 0

JCR@2023

ESI HC Threshold:236

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 31

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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