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author:

Li, Z. (Li, Z..) [1] | Peng, B. (Peng, B..) [2] | Zhang, T. (Zhang, T..) [3] | Li, H. (Li, H..) [4] | Li, L. (Li, L..) [5] | Wen, C. (Wen, C..) [6] | Chen, K. (Chen, K..) [7]

Indexed by:

Scopus

Abstract:

Glass and glass-ceramic are one of the key sealing materials for solid oxide fuel cells (SOFCs) and they need to meet stringent requirements for long-term operation at high temperatures. Here, we report for the first time the incorporation of aluminum nitride (AlN) dopant into borosilicate glasses and glass-ceramics so as to tailor their basic properties and sealing performance. The results show the AlN-doped glass-ceramics exhibit remarkably enhanced thermal stability and chemical compatibility when adhering to Y2O3-ZrO2 electrolyte. The electrical conductivity is also significantly reduced by the AlN doping, and the conductivity of 15 wt.% AlN-doped glass-ceramic is nearly two orders of magnitude lower than that of the undoped glass-ceramic. This work indicates that AlN doping is an effective strategy to obtain a reliable borosilicate glass-ceramics for SOFCs. © 2019 Elsevier Ltd

Keyword:

AlN; Crystallization; Sealing glass-ceramic; Solid oxide fuel cell

Community:

  • [ 1 ] [Li, Z.]College of Materials Science and Engineering, Fuzhou University, and Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, Fuzhou, 350116, China
  • [ 2 ] [Peng, B.]College of Materials Science and Engineering, Fuzhou University, and Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, Fuzhou, 350116, China
  • [ 3 ] [Zhang, T.]College of Materials Science and Engineering, Fuzhou University, and Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, Fuzhou, 350116, China
  • [ 4 ] [Li, H.]Fujian Applied Technology Engineering Center of Power Battery Materials, Fujian College of Water Conservancy and Electric Power, Yongan, Fujian 366000, China
  • [ 5 ] [Li, L.]College of Materials Science and Engineering, Fuzhou University, and Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, Fuzhou, 350116, China
  • [ 6 ] [Wen, C.]College of Materials Science and Engineering, Fuzhou University, and Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, Fuzhou, 350116, China
  • [ 7 ] [Chen, K.]College of Materials Science and Engineering, Fuzhou University, and Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province University, Fuzhou, 350116, China

Reprint 's Address:

  • [Wen, C.]College of Materials Science and Engineering, Fuzhou University, and Key Laboratory of Eco-Materials Advanced Technology (Fuzhou University), Fujian Province UniversityChina

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Source :

Journal of the European Ceramic Society

ISSN: 0955-2219

Year: 2019

Issue: 14

Volume: 39

Page: 4194-4201

4 . 4 9 5

JCR@2019

5 . 8 0 0

JCR@2023

ESI HC Threshold:236

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 11

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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