Viedma Ripening of Chiral Coordination Polymers Based on Achiral Molecules - Details

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Abstract：

When　the　chiral　coordination　polymers　were　composed　of　achiral　molecules,　the　deracemization　of　the　bulk　product　remains　a　great　challenge　if　without　any　chiral　induction.　The　Viedma　ripening　theory　was　adopted　herein　to　help　the　achievement　of　mirror　symmetry　breaking　for　the　bulk　chirality　of　two　chiral　coordination　polymers.　The　enantiomeric　excess　of　the　bulk　chirality　for　the　first　compound　is　about　100%,　which　means　absolute　asymmetric　synthesis.　The　deracemization　degree　of　the　bulk　chirality　for　the　second　compound　fluctuates　occasionally.　Further　study　has　discussed　the　different　deracemization　degree　of　the　bulk　chirality　for　two　compounds　with　the　consideration　of　enantioselective　incorporation　in　crystal　cluster.　Copyright　©　2019　American　Chemical　Society.

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[ 1 ] [Wu, S.-T.]Institute of Optical Crystalline Materials, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 2 ] [Wu, S.-T.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 3 ] [Zhang, Y.-S.]Institute of Optical Crystalline Materials, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 4 ] [Zhang, B.]Institute of Optical Crystalline Materials, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 5 ] [Hu, X.-L.]Institute of Optical Crystalline Materials, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 6 ] [Huang, X.-H.]Institute of Optical Crystalline Materials, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 7 ] [Huang, C.-C.]Institute of Optical Crystalline Materials, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 8 ] [Zhuang, N.-F.]Institute of Optical Crystalline Materials, College of Chemistry, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address：

[Wu, S.-T.]Institute of Optical Crystalline Materials, College of Chemistry, Fuzhou UniversityChina

Email：

shutingwu@fzu.edu.cn

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Crystal Growth and Design

ISSN： 1528-7483

Year： 2019

Issue： 5

Volume： 19

Page： 2537-2541

4 . 0 8 9

JCR@2019

3 . 2 0 0

JCR@2023

ESI HC Threshold：184

JCR Journal Grade：1

CAS Journal Grade：2

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ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 2

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