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author:

Wang, B. (Wang, B..) [1] | Ding, Y. (Ding, Y..) [2] | Deng, Z. (Deng, Z..) [3] | Li, Z. (Li, Z..) [4]

Indexed by:

Scopus PKU CSCD

Abstract:

The NiS/CQDs nanocomposite (CQDs represents carbon quantum dots), with a mass ratio of NiS/CQDs to be 1.19:1 based on the ICP result, was obtained via a facile hydrothermal method from a mixture of CQDs, Ni(OAc)2 and Na2S. The self-assembly of ZnIn2S4 microspheres on the surface of NiS/CQDs was realized under microwave conditions to obtain a ternary NiS/CQDs/ZnIn2S4 nanocomposite. The as-obtained NiS/CQDs/ZnIn2S4 nanocomposite was fully characterized, and its photocatalytic hydrogen evolution under visible light irradiation was investigated. The ternary NiS/CQDs/ZnIn2S4 nanocomposite showed superior photocatalytic activity for hydrogen evolution than ternary CQDs/NiS/ZnIn2S4, which was obtained by deposition of NiS in the preformed CQDs/ZnIn2S4. The superior photocatalytic performance of ternary NiS/CQDs/ZnIn2S4 is ascribed to the introduction of CQDs, which act as a bridge to promote the vectorial transfer of photo-generated electrons from ZnIn2S4 to NiS. This result suggests that the rational design and fabrication of ternary CQDs-based systems are important for the efficient photocatalytic hydrogen evolution. This study provides a strategy for developing highly efficient noble-metal-free photocatalysts for hydrogen evolution using CQDs as a bridge to promote the charge transfer in the nanocomposite. "© 2019, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. "

Keyword:

Carbon quantum dots; Hydrogen evolution; NiS; Photocatalysis; ZnIn2S4

Community:

  • [ 1 ] [Wang, B.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, China
  • [ 2 ] [Ding, Y.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, China
  • [ 3 ] [Deng, Z.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, China
  • [ 4 ] [Li, Z.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, China

Reprint 's Address:

  • [Wang, B.]Research Institute of Photocatalysis, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

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Source :

Chinese Journal of Catalysis

ISSN: 0253-9837

CN: 21-1601/O6

Year: 2019

Issue: 3

Volume: 40

Page: 335-342

6 . 1 4 6

JCR@2019

1 5 . 7 0 0

JCR@2023

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 93

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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