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author:

Shi, J. (Shi, J..) [1] | Sun, M. (Sun, M..) [2] | Hu, H. (Hu, H..) [3]

Indexed by:

Scopus

Abstract:

Carbon inlaid composites (C-Mn3O4/MnO) were prepared via igniting manganese acetate anhydrous ethanol solution in a beaker, and the resulting nanocomposites present homogeneous dispersion and stable property. The successful fabrication of the as-prepared samples was demonstrated by x-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscopy (TEM), and x-ray photoelectron spectroscopy (XPS). Various electrochemical measurements including cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy (EIS) were carried out. The maximum specific capacitance value of the C-Mn3O4/MnO composites can reach up to 204 F g-1 at a current density of 1 A g-1, which is much higher than that of Mn3O4/MnO composites (90 F g-1). The incorporated carbon improves the electrochemical performance and effectively decreases the charge transfer resistance of the composites (0.67 Ω) compared with pure Mn3O4/MnO composites (42.4 Ω). Surprisingly, as the number of cycles increase, the specific capacitance of C-Mn3O4/MnO composites become larger with a 188.3% of the initial specific capacitance value. This study develops a novel and facile method to fabricate composites of carbon and manganic oxide which have potential application in supercapacitor. © 2018 IOP Publishing Ltd.

Keyword:

C-Mn3O4/MnO; composite materials; electrochemical performance; energy storage and conversion; supercapacitor

Community:

  • [ 1 ] [Shi, J.]School of Materials Engineering, Shanghai University of Engineering Science, Shanghai, 201620, China
  • [ 2 ] [Sun, M.]School of Materials Engineering, Shanghai University of Engineering Science, Shanghai, 201620, China
  • [ 3 ] [Sun, M.]Shanghai Collaborative Innovation Center of Laser Advanced Manufacturing Technology, Shanghai, 201620, China
  • [ 4 ] [Sun, M.]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China
  • [ 5 ] [Hu, H.]School of Materials Engineering, Shanghai University of Engineering Science, Shanghai, 201620, China

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Source :

Materials Research Express

ISSN: 2053-1591

Year: 2019

Issue: 3

Volume: 6

1 . 9 2 9

JCR@2019

1 . 8 0 0

JCR@2023

ESI HC Threshold:236

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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