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author:

Zhang, X. (Zhang, X..) [1] | Ge, M. (Ge, M..) [2] | Dong, J. (Dong, J..) [3] | Huang, J. (Huang, J..) [4] | He, J. (He, J..) [5] | Lai, Y. (Lai, Y..) [6]

Indexed by:

Scopus

Abstract:

The primary challenge of photocatalytic hydrogen generation is to exploit a catalyst with good durability and low cost. Here, we designed a facile and efficient process of loading silver nanoparticles (Ag NPs) in situ on the core-shell nanocomposite of the elongated titanium dioxide nanotubes with a carbon layer (C@TiO2 NTs) by polydopamine (PDA) without addition of any binder. The combination of C@TiO2 NTs with Ag NPs has excellent performance toward photocatalytic hydrogen production and degradation of rhodamine B (RhB) under visible light irradiation. The characterizations (SEM, TAM, XRD, XPS, etc.) showed that the carbon layer on nanotubes could conformably cover the whole of TiO2 NTs to form the core-shell structure, which not only prevented Ag NPs from aggregating but also acted as the electronic transport channel. Meanwhile, Ag NPs were uniformly distributed on the surface of C@TiO2 NTs. In conclusion, under the synergistic effect of Ag nanoparticles and the outer-carbon layer, the utilization efficiency of visible light has been enhanced, and the recombination of electrons/holes has been suppressed for Ag@C@TiO2 NTs nanocomposites. Therefore, the degradation efficiency of RhB and hydrogen generation rate are 2.5 times and 4.8 times higher than those of the pure TiO2 NTs, respectively. This work may provide fruitful experience for developing a novel strategy into the design and fabrication of stable and highly active visible-light catalysts with noble metal modification toward sustainable hydrogen production in the energy filed. © Copyright 2018 American Chemical Society.

Keyword:

Ag nanoparticle; Carbon shell; Core-shell structure; Elongated TiO2 nanotube; Visible-light-induced photocatalyst

Community:

  • [ 1 ] [Zhang, X.]National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou, 215123, China
  • [ 2 ] [Ge, M.]National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou, 215123, China
  • [ 3 ] [Dong, J.]National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou, 215123, China
  • [ 4 ] [Huang, J.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [He, J.]National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou, 215123, China
  • [ 6 ] [Lai, Y.]National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow University, Suzhou, 215123, China
  • [ 7 ] [Lai, Y.]College of Chemical Engineering, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address:

  • [Lai, Y.]National Engineering Laboratory for Modern Silk, College of Textile and Clothing Engineering, Soochow UniversityChina

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Source :

ACS Sustainable Chemistry and Engineering

ISSN: 2168-0485

Year: 2019

Issue: 1

Volume: 7

Page: 558-568

7 . 6 3 2

JCR@2019

7 . 1 0 0

JCR@2023

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 41

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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