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author:

Lan, S. (Lan, S..) [1] | Yan, Y. (Yan, Y..) [2] | Yang, H. (Yang, H..) [3] | Zhang, G. (Zhang, G..) [4] | Ye, Y. (Ye, Y..) [5] | Li, F. (Li, F..) [6] | Chen, H. (Chen, H..) [7] | Guo, T. (Guo, T..) [8]

Indexed by:

Scopus

Abstract:

Low-power complementary organic circuits need to combine p-channel organic field-effect transistors (OFETs) and n-channel OFETs, which are based on p-type and n-type organic semiconductors, respectively. Unfortunately, the performance of n-type organic semiconductors still lags behind that of p-type organic semiconductors. In this work, the performance of solution-processed n-type OFETs was improved via a facile effective route, by blending a p-type organic semiconductor into the n-type polymer semiconductor. The effect of the p-type organic semiconductor additive on the morphology and charge transport was systematically investigated. It showed that the mobility, on/off ratio and stability of the n-type OFETs were significantly improved with incorporation of the p-type semiconductor. The p-type organic semiconductor functioned as a trap center for minority holes and decreased the trap density of the dielectric surface, resulting in an enhancement of the OFET performance. Moreover, blending with an appropriate amount of p-type organic semiconductor also benefited to reset polymer semiconductors stacking order into the direction that promoted charge transport. However, excess p-type semiconductor addition deteriorated the n-channel characteristics due to the formation of a percolation network, providing a pathway for hole transport. To the best of our knowledge, this is the first report about improving the performance of n-type polymer transistors by simply blending with a p-type organic semiconductor. © The Royal Society of Chemistry.

Keyword:

Community:

  • [ 1 ] [Lan, S.]Institute of Optoelectronic Display, National and Local United Engineering Lab of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350002, China
  • [ 2 ] [Yan, Y.]Institute of Optoelectronic Display, National and Local United Engineering Lab of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350002, China
  • [ 3 ] [Yang, H.]Institute of Optoelectronic Display, National and Local United Engineering Lab of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350002, China
  • [ 4 ] [Zhang, G.]Institute of Optoelectronic Display, National and Local United Engineering Lab of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350002, China
  • [ 5 ] [Ye, Y.]Institute of Optoelectronic Display, National and Local United Engineering Lab of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350002, China
  • [ 6 ] [Li, F.]Institute of Optoelectronic Display, National and Local United Engineering Lab of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350002, China
  • [ 7 ] [Chen, H.]Institute of Optoelectronic Display, National and Local United Engineering Lab of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350002, China
  • [ 8 ] [Guo, T.]Institute of Optoelectronic Display, National and Local United Engineering Lab of Flat Panel Display Technology, Fuzhou University, Fuzhou, 350002, China

Reprint 's Address:

  • [Chen, H.]Institute of Optoelectronic Display, National and Local United Engineering Lab of Flat Panel Display Technology, Fuzhou UniversityChina

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Source :

Journal of Materials Chemistry C

ISSN: 2050-7534

Year: 2019

Issue: 15

Volume: 7

Page: 4543-4550

7 . 0 5 9

JCR@2019

5 . 7 0 0

JCR@2023

ESI HC Threshold:236

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 42

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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