Ultra-small Pd nanoparticles derived from a supramolecular assembly for enhanced electrochemical reduction of CO2 to CO - Details

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Abstract：

Ultra-small　Pd　nanoparticles　were　successfully　prepared　through　reduction　of　a　supramolecular　assembly　formed　between　the　macrocyclic　decamethylcucurbit[5]uril　(Me10CB[5])　and　[PdCl4]2-　anions　via　H-bonds.　The　final　Pd　NPs　exhibit　excellent　activity　and　stability　toward　the　electrochemical　reduction　of　CO2　to　CO.　This　work　provides　a　new　strategy　for　the　preparation　of　nanocatalysts.　This　journal　is　©　2019　The　Royal　Society　of　Chemistry.

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[ 1 ] [Chen, R.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 2 ] [Chen, R.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 3 ] [Cao, M.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 4 ] [Yang, W.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 5 ] [Yang, W.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 6 ] [Wang, H.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 7 ] [Zhang, S.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 8 ] [Li, H.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 9 ] [Cao, R.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China

Reprint 's Address：

[Cao, M.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesChina

Email：

mncao@fjirsm.ac.cn

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Chemical Communications

ISSN： 1359-7345

Year： 2019

Issue： 66

Volume： 55

Page： 9805-9808

5 . 9 9 6

JCR@2019

4 . 3 0 0

JCR@2023

ESI HC Threshold：184

JCR Journal Grade：1

CAS Journal Grade：2

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 1

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