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author:

Chen, S.-C. (Chen, S.-C..) [1] | Zhang, S. (Zhang, S..) [2] | Zheng, Q. (Zheng, Q..) [3]

Indexed by:

Scopus CSCD

Abstract:

Recently, perovskite solar cells (PVSCs) based on CsPbI2Br have attracted increasing attention owing to their good balance between efficiency and stability. Solution-processed CsPbI2Br perovskites usually contain various defects which need passivation for PVSCs with high-performance as well as good stability. Since the degradation of perovskite films usually begins at the grain boundaries, here we report a facile defect passivation strategy by spin-coating a KF solution on the CsPbI2Br perovskite surface. The deposited KF salt mostly locates at the grain boundaries of the perovskite surface, resulting in PVSCs with improved stability. Both steady-state and time-resolved photoluminescence results suggest that the defects of perovskite were significantly passivated by KF treatment. Consequently, the best-performance PVSC based on CsPbI2Br with KF treatment shows an enhanced power conversion efficiency (PCE) of 15.01% with a larger open circuit voltage (VOC) of 1.26 V in comparison with the pristine CsPbI2Br-based counterpart which exhibits an inferior PCE of 14.14% with a VOC of 1.18 V. © 2020, Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature.

Keyword:

defect passivation; energy conversion; fluorides; grain boundary; perovskites

Community:

  • [ 1 ] [Chen, S.-C.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 2 ] [Zhang, S.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  • [ 3 ] [Zhang, S.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Zheng, Q.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China

Reprint 's Address:

  • [Zheng, Q.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesChina

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Source :

Science China Materials

ISSN: 2095-8226

Year: 2020

Issue: 5

Volume: 63

Page: 719-727

8 . 2 7 3

JCR@2020

6 . 8 0 0

JCR@2023

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 29

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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