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author:

Bai, Z. (Bai, Z..) [1] | Shen, S. (Shen, S..) [2] | Chen, L. (Chen, L..) [3] | Au, C.-T. (Au, C.-T..) [4] | Yin, S.-F. (Yin, S.-F..) [5]

Indexed by:

Scopus PKU CSCD

Abstract:

Benzaldehyde is an important fine chemical widely used in spices, dyes, medicine, pesticides, auxiliaries and synthetic materials. Heterogenous photocatalytic synthesis of benzaldehyde from toluene has been drawing increasing attention due to the relatively mild reaction conditions, high selectivity and easy recycling of the catalyst. Centered on the development of efficient photocatalysts, this article reviews the research progress of the photocatalytic selective oxidation of toluene in the past ten years. Different types of photocatalysts (including TiO2-based, Bi-based, CdS-based, g-C3N4-based, etc.) are discussed, along with the design philosophies and reaction mechanisms. Finally, being a longtime participant in this field, we provide our prospects on the design and preparation of the photocatalysts, the reaction mechanism, as well as the development of high efficiency photocatalytic reactors. © 2020 Science China Press. All Rights Reserved.

Keyword:

Benzaldehyde; Heterogeneous photocatalysis; Photocatalysis; Selective oxidation; Toluene

Community:

  • [ 1 ] [Bai, Z.]State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China
  • [ 2 ] [Shen, S.]State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China
  • [ 3 ] [Chen, L.]State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China
  • [ 4 ] [Au, C.-T.]School of Petrochemical Engineering, Fuzhou University, Fuzhou, 350002, China
  • [ 5 ] [Yin, S.-F.]State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, China

Reprint 's Address:

  • [Shen, S.]State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan UniversityChina

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Source :

Scientia Sinica Chimica

ISSN: 1674-7224

Year: 2020

Issue: 2

Volume: 50

Page: 223-234

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 5

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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