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Benzaldehyde is an important fine chemical widely used in spices, dyes, medicine, pesticides, auxiliaries and synthetic materials. Heterogenous photocatalytic synthesis of benzaldehyde from toluene has been drawing increasing attention due to the relatively mild reaction conditions, high selectivity and easy recycling of the catalyst. Centered on the development of efficient photocatalysts, this article reviews the research progress of the photocatalytic selective oxidation of toluene in the past ten years. Different types of photocatalysts (including TiO2-based, Bi-based, CdS-based, g-C3N4-based, etc.) are discussed, along with the design philosophies and reaction mechanisms. Finally, being a longtime participant in this field, we provide our prospects on the design and preparation of the photocatalysts, the reaction mechanism, as well as the development of high efficiency photocatalytic reactors. © 2020 Science China Press. All Rights Reserved.
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Scientia Sinica Chimica
ISSN: 1674-7224
Year: 2020
Issue: 2
Volume: 50
Page: 223-234
Cited Count:
SCOPUS Cited Count: 5
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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