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author:

Lin, L.-D. (Lin, L.-D..) [1] | Zhao, D. (Zhao, D..) [2] | Li, X.-X. (Li, X.-X..) [3] | Zheng, S.-T. (Zheng, S.-T..) [4]

Indexed by:

Scopus

Abstract:

During the past decade, research on the design and synthesis of zeolite-like metal–organic frameworks (ZMOFs) has developed greatly. As an important subclass of ZMOFs, zeolite-like cluster organic frameworks (ZCOFs) built from 4-connected metal-cluster secondary building units (SBUs) and appropriate linear organic ligand bridges have attracted sustained interest, because such materials not only integrate the merits of inorganic zeolites, ZMOFs, and metal clusters, including interesting topologies, high surface areas, extra-large cavities and channels, structural tunability, and unique physicochemical properties from various metal clusters, but also open up a new avenue to design and fabricate hybrid zeolite-like materials that have many potential applications in material sciences. In this review, recent developments in ZCOFs are summarized by classifying the ZCOFs into four categories according to the composition of the SBUs: 1) ZCOFs based on metal–halide cluster SBUs, 2) ZCOFs based on metal–oxygen cluster SBUs, 3) ZCOFs based on metal–chalcogen cluster SBUs, and 4) ZCOFs based on mixed types of metal-cluster SBUs. Besides, challenges associated with the design and synthesis of ZCOFs and the vast potential of this area are also discussed. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Keyword:

chalcogens; cluster compounds; cluster organic frameworks; metal–halide clusters; zeolite analogues

Community:

  • [ 1 ] [Lin, L.-D.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fujian, Fuzhou 350108, China
  • [ 2 ] [Zhao, D.]Fuqing Branch of Fujian Normal University, Fujian, Fuqing 350300, China
  • [ 3 ] [Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fujian, Fuzhou 350108, China
  • [ 4 ] [Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fujian, Fuzhou 350108, China

Reprint 's Address:

  • [Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

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Source :

Chemistry - A European Journal

ISSN: 0947-6539

Year: 2019

Issue: 2

Volume: 25

Page: 442-453

4 . 8 5 7

JCR@2019

3 . 9 0 0

JCR@2023

ESI HC Threshold:184

JCR Journal Grade:1

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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