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author:

Lin, C. (Lin, C..) [1] | Wang, H. (Wang, H..) [2] | Wang, P. (Wang, P..) [3] | Wu, X. (Wu, X..) [4] | Lin, T. (Lin, T..) [5] | Sa, B. (Sa, B..) [6] | Cheng, Y. (Cheng, Y..) [7] | Zheng, X. (Zheng, X..) [8] | Yu, X. (Yu, X..) [9] | Fang, C. (Fang, C..) [10]

Indexed by:

Scopus

Abstract:

Dy3+-doped K0.5Na0.5NbO3-Ba(Sc0.5Nb0.5)O3 transparent ferroelectric ceramics, a novel smart white-lighting (WL) photochromic (PC) material, were prepared by conventional pressureless sintering. The ceramics exhibit high optical transmittance (~67% at 1800 nm), good photoluminescence (PL) performance, high-quality WL, and moderate electrical properties. Meanwhile, high-contrast modulations of optical transmittance and PL intensity (with the maximal modulating values of 20.5% and 57.4%, respectively) have been realized via PC behavior by alternating the illumination of UV light and thermal stimulus. In particular, the reversible modulations of WL intensity, color coordinates, correlated color temperature, and color purity have been achieved through the PC regulation to the intensity ratio of yellow/blue emission. Definitively, based on the effect of intrinsic defects and extrinsic defects (Ba4+/Sc3-x) on the PL properties, the PC mechanism in KNN-based material has been further complemented. The transparent ceramics should be a promising material in white LEDs and optoelectronic multifunctional devices. © 2020 American Ceramic Society (ACERS)

Keyword:

intrinsic/extrinsic defects; KNN; photochromic behavior; transparent ceramics; white lighting modulation

Community:

  • [ 1 ] [Lin, C.]Department of Material Science and Engineering, Fuzhou University, Fuzhou, China
  • [ 2 ] [Wang, H.]Department of Material Science and Engineering, Fuzhou University, Fuzhou, China
  • [ 3 ] [Wang, P.]Department of Material Science and Engineering, Fuzhou University, Fuzhou, China
  • [ 4 ] [Wu, X.]Department of Material Science and Engineering, Fuzhou University, Fuzhou, China
  • [ 5 ] [Lin, T.]Department of Material Science and Engineering, Fuzhou University, Fuzhou, China
  • [ 6 ] [Sa, B.]Department of Material Science and Engineering, Fuzhou University, Fuzhou, China
  • [ 7 ] [Cheng, Y.]Fujian Institute of Research on the Structure, Fuzhou, China
  • [ 8 ] [Zheng, X.]Department of Material Science and Engineering, Fuzhou University, Fuzhou, China
  • [ 9 ] [Yu, X.]National Analysis Center for Iron & Steel, Central Iron and Steel Research Institute, Beijing, China
  • [ 10 ] [Fang, C.]Faculty of Printing, Packing Engineering and Digital Media Technology, Xi'an University of Technology, Xi'an, China

Reprint 's Address:

  • [Wu, X.]Department of Material Science and Engineering, Fuzhou UniversityChina

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Source :

Journal of the American Ceramic Society

ISSN: 0002-7820

Year: 2020

3 . 7 8 4

JCR@2020

3 . 5 0 0

JCR@2023

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 54

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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