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author:

Peng, H. (Peng, H..) [1] | Zhang, Y. (Zhang, Y..) [2] | Chen, Y. (Chen, Y..) [3] | Zhang, J. (Zhang, J..) [4] | Jiang, H. (Jiang, H..) [5] | Chen, X. (Chen, X..) [6] | Zhang, Z. (Zhang, Z..) [7] | Zeng, Y. (Zeng, Y..) [8] | Sa, B. (Sa, B..) [9] | Wei, Q. (Wei, Q..) [10] | Lin, J. (Lin, J..) [11] | Guo, H. (Guo, H..) [12]

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Scopus

Abstract:

Polarization of lithium-sulfur (Li-S) batteries consumes energy density upon cycling, which precludes their practical application in state-of-the-art devices. Herein a conformal zinc sulfide/reduced graphene oxide/elemental sulfur (ZnS/rGO/S) composite is synthesized and used as cathode materials in Li-S batteries. The synergetic regulation of ohmic, concentration, and electrochemical polarization decreases the overpotential and improves the cycling performance of the Li||ZnS/rGO/S cell. Combining theoretical calculations and experimental results, it is revealed that the ZnS spheres can absorb lithium polysulfide (LPS) intermediates, catalyze LPS conversion, and provide fast electronic/ionic diffusion kinetics. The ZnS/rGO/S cathode is further applied in pouch Li-S cells, demonstrating the practicability of sulfur cathodes with reduced polarization. © 2020 Elsevier Ltd

Keyword:

Adsorption; Catalysis; Li-S battery; Polarization; Zinc sulfide

Community:

  • [ 1 ] [Peng, H.]College of Materials, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, Xiamen University, Xiamen, Fujian 361005, China
  • [ 2 ] [Zhang, Y.]College of Materials, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, Xiamen University, Xiamen, Fujian 361005, China
  • [ 3 ] [Chen, Y.]College of Materials, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, Xiamen University, Xiamen, Fujian 361005, China
  • [ 4 ] [Zhang, J.]College of Materials, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, Xiamen University, Xiamen, Fujian 361005, China
  • [ 5 ] [Jiang, H.]College of Materials, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, Xiamen University, Xiamen, Fujian 361005, China
  • [ 6 ] [Chen, X.]College of Materials, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, Xiamen University, Xiamen, Fujian 361005, China
  • [ 7 ] [Zhang, Z.]College of Materials, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, Xiamen University, Xiamen, Fujian 361005, China
  • [ 8 ] [Zeng, Y.]College of Materials, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, Xiamen University, Xiamen, Fujian 361005, China
  • [ 9 ] [Sa, B.]Multiscale Computational Materials Facility, College of Materials Science and Engineering, Fuzhou University, Fuzhou, Fujian 350100, China
  • [ 10 ] [Wei, Q.]College of Materials, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, Xiamen University, Xiamen, Fujian 361005, China
  • [ 11 ] [Lin, J.]College of Materials, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, Xiamen University, Xiamen, Fujian 361005, China
  • [ 12 ] [Guo, H.]College of Materials, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, Xiamen University, Xiamen, Fujian 361005, China

Reprint 's Address:

  • [Lin, J.]College of Materials, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, Xiamen University, College of Materials, Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, Xiamen UniversityChina

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Source :

Materials Today Energy

ISSN: 2468-6069

Year: 2020

Volume: 18

7 . 3 1 1

JCR@2020

9 . 0 0 0

JCR@2023

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 61

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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