Synthesis and characterization of N-(arylmethylene)-benzimidazole/imidazole-borane compounds - Details

author：

Liu, W.-M. (Liu, W.-M..) ^[1] | Zhang, M. (Zhang, M..) ^[2] | Yan, J.-F. (Yan, J.-F..) ^[3] | Lin, C.-X. (Lin, C.-X..) ^[4] | Yuan, Y.-F. (Yuan, Y.-F..) ^[5]

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Abstract：

N-(arylmethylene)-benzimidazole/imidazole-borane　compounds　(7-10)　based　on　ferrocene/benzene　were　synthesized　in　a　cost-effective　way　by　reacting　N-(arylmethylene)-benzimidazole/imidazoles　with　ammonium　sulfate　((NH4)2SO4)　and　sodium　borohydride　(NaBH4).　The　structures　of　compounds　7-9　were　determined　by　X-ray　crystallography.　Four　compounds　displayed　high　thermal　decomposition　temperatures　(182-256°C)　according　to　the　thermogravimetry　(TG)　measurements.　Interestingly,　these　compounds　showed　promising　applications　as　potential　propellant　due　to　their　spontaneous　combustion　upon　contact　concentrated　HNO3　(≥　95　%)　and　catalytic　effect　on　the　thermal　degradation　of　ammonium　perchlorate　(AP).　©　2020　Elsevier　B.V.

Keyword：

Borane; Combustion test;Catalytic effect on ammonium perchlorate; Ferrocene; Imidazole; Thermal properties

Community：

[ 1 ] [Liu, W.-M.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Zhang, M.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 3 ] [Yan, J.-F.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 4 ] [Lin, C.-X.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Department of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 5 ] [Yuan, Y.-F.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Department of Chemistry, Fuzhou University, Fuzhou, 350108, China

Reprint 's Address：

[Lin, C.-X.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), Department of Chemistry, Fuzhou UniversityChina

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Source ：

Journal of Organometallic Chemistry

ISSN： 0022-328X

Year： 2020

Volume： 927

2 . 1 0 0

JCR@2023

ESI HC Threshold：160

JCR Journal Grade：2

CAS Journal Grade：3

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WoS CC Cited Count：

SCOPUS Cited Count： 6

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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