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author:

Lyu, H. (Lyu, H..) [1] | Hu, K. (Hu, K..) [2] | Chu, Q. (Chu, Q..) [3] | Su, Z. (Su, Z..) [4] | Xie, Z. (Xie, Z..) [5]

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Scopus

Abstract:

In this paper, an ionic liquid mediated molecularly imprinted polymer (IL-MIP) was prepared, in which synthesis system 1-butyl-3-methylimidazolium tetrafluoroborate (IL) was introduced to improve its selectivity and adsorption for the target. The structures of the prepared materials were characterized by SEM, BET, 13CNMR and FTIR, and the adsorption performance of the resultant IL-MIP for BPA and its analogues (phenol, 4-NP, 4-CAP and 1-naphthol) in strong polar media were investigated in detail. The experimental data showed that the adsorption capacities of IL-MIP and molecularly imprinted polymer (MIP) for Bisphenol A (BPA) were 116.16 mg/g and 87.30 mg/g, with imprinting factor of 3.77 and 2.72, respectively. In addition, several other competitive analogues with different polarities (phenol, 4-NP, 4-CAP and 1-naphthol) were chosen to evaluate the selectivity of IL-MIP and the experimental results demonstrated that the synthesized IL-MIP displayed selectivity toward BPA and against analogue molecules. This work provided a simple and effective method to selectively extract BPA from aqueous medium or strong polar organic solvent. © 2020 Elsevier B.V.

Keyword:

BPA; Ionic liquid; Molecular imprinted polymer

Community:

  • [ 1 ] [Lyu, H.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Lyu, H.]Key Laboratory of Eco-materials Advanced Technology (Fuzhou University), Fujian Province University, Fuzhou, Fujian 350108, China
  • [ 3 ] [Hu, K.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 4 ] [Chu, Q.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 5 ] [Su, Z.]College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 6 ] [Xie, Z.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China

Reprint 's Address:

  • [Lyu, H.]College of Materials Science and Engineering, Fuzhou UniversityChina

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Source :

Microchemical Journal

ISSN: 0026-265X

Year: 2020

Volume: 158

4 . 8 2 1

JCR@2020

4 . 9 0 0

JCR@2023

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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