Self-Assembly of Lanthanide-Covalent Organic Polyhedra: Chameleonic Luminescence and Efficient Catalysis - Details

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Abstract：

A　series　of　multinuclear　lanthanide-covalent　organic　polyhedra　(LnCOPs),　including　pillar-typed　triangular　prisms　1-Ln3　and　tetrahedra　2-Ln4　(Ln　=　LaIII,　SmIII,　EuIII),　have　been　constructed　for　the　first　time,　through　either　one-pot　subcomponent　self-assembly　or　postassembly　metalation.　In　contrast　to　the　known　tetrahedral　cages　based　on　transition　metals,　the　pillar-typed　polyhedra　were　favored　from　the　same　organic　components　in　the　presence　of　lanthanides.　Besides　this,　facile　transmetalations　between　the　1-Ln3　polyhedra　endow　cascade　chameleonic　luminescence.　Meanwhile,　the　open　metal　sites　and　pendent　amine　groups　on　1-Ln3　enable　these　polyhedra　to　catalyze　the　Henry　reaction　efficiently.　©　2020　American　Chemical　Society.

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[ 1 ] [Han, S.-L.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Han, S.-L.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 3 ] [Yang, J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 4 ] [Tripathy, D.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 5 ] [Guo, X.-Q.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 6 ] [Guo, X.-Q.]Fujian College, University of Chinese Academy of Sciences, Beijing, 100049, China
[ 7 ] [Hu, S.-J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 8 ] [Hu, S.-J.]Fujian College, University of Chinese Academy of Sciences, Beijing, 100049, China
[ 9 ] [Li, X.-Z.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 10 ] [Cai, L.-X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 11 ] [Zhou, L.-P.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 12 ] [Sun, Q.-F.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 13 ] [Sun, Q.-F.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
[ 14 ] [Sun, Q.-F.]Fujian College, University of Chinese Academy of Sciences, Beijing, 100049, China

Reprint 's Address：

[Sun, Q.-F.]College of Chemistry, Fuzhou UniversityChina

Email：

qfsun@fjirsm.ac.cn

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Inorganic Chemistry

ISSN： 0020-1669

Year： 2020

Issue： 19

Volume： 59

Page： 14023-14030

5 . 1 6 5

JCR@2020

4 . 3 0 0

JCR@2023

ESI HC Threshold：160

JCR Journal Grade：1

CAS Journal Grade：1

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SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 1

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