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author:

Yu, L. (Yu, L..) [1] | Zhang, W. (Zhang, W..) [2] | Lv, J. (Lv, J..) [3] | Liu, X. (Liu, X..) [4] | Li, Y. (Li, Y..) [5] | Wei, M. (Wei, M..) [6]

Indexed by:

Scopus

Abstract:

The tunnel structural titanates are absorbing as electrode materials for rechargeable batteries. However, the electronic conductivity and lithium-ion diffusion of these materials are seriously influenced by tunnel cations (Na+, K+), which are not acquainted imperfectly for their effect in lithium-ion batteries. In the present research, the layered structural K2Ti6O13(KTO) nanowires with a high aspect ratio and a large surface area have been synthesized through a general hydrothermal route. When applied as an anode material for lithium-ion intercalation, this material exhibited high and stable capacity, prominent cycling stability, and remarkable rate capabilities. Even at a high current density of 0.5 A g−1, a large reversible capacity of 134.6 mA h g−1 was acquired after 1000 cycles. These might be attributed to the fact that 1D nanostructural K2Ti6O13 with a high aspect ratio provides more surface reaction sites as well as increase the charge-transfer ability, and the presence of K+ in tunnels of K2Ti6O13 can efficiently improve the electronic conductivity and Li+ diffusivity. © 2020 Elsevier B.V.

Keyword:

Electrochemical properties; K2Ti6O13; Lithium-ion batteries; Nanowires; Tunnel

Community:

  • [ 1 ] [Yu, L.]Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, Fuzhou University, Minhou, Fuzhou, Fujian 350002, China
  • [ 2 ] [Zhang, W.]Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, Fuzhou University, Minhou, Fuzhou, Fujian 350002, China
  • [ 3 ] [Lv, J.]Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, Fuzhou University, Minhou, Fuzhou, Fujian 350002, China
  • [ 4 ] [Liu, X.]Science and Technology on Power Sources Laboratory, Tianjin Institute of Power Sources, Haitai Industrial Park, Xiqing District, Tianjin, 300384, China
  • [ 5 ] [Li, Y.]Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, Fuzhou University, Minhou, Fuzhou, Fujian 350002, China
  • [ 6 ] [Wei, M.]Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, Fuzhou University, Minhou, Fuzhou, Fujian 350002, China
  • [ 7 ] [Wei, M.]Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou, Jiangsu 213164, China

Reprint 's Address:

  • [Liu, X.]Science and Technology on Power Sources Laboratory, Tianjin Institute of Power Sources, Fujian Provincial Key Laboratory of Electrochemical Energy Storage Materials, Fuzhou University, Haitai Industrial Park, Xiqing District, China

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Source :

Journal of Electroanalytical Chemistry

ISSN: 1572-6657

Year: 2020

Volume: 874

4 . 4 6 4

JCR@2020

4 . 1 0 0

JCR@2023

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 6

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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