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author:

Zhao, Z.-H. (Zhao, Z.-H..) [1] | Wang, J.-B. (Wang, J.-B..) [2] | Pan, J.-B. (Pan, J.-B..) [3] | Tan, Y.-X. (Tan, Y.-X..) [4] | Chen, L. (Chen, L..) [5] | Guo, J.-K. (Guo, J.-K..) [6] | Shen, S. (Shen, S..) [7] | Au, C.-T. (Au, C.-T..) [8] | Yin, S.-F. (Yin, S.-F..) [9]

Indexed by:

Scopus

Abstract:

Z-scheme Ag3PO4/Ag/MoO3-x photocatalyst was prepared by deposition of Ag and Ag3PO4 nanoparticles on the surface of MoO3-x nanosheets. With Ag mediation between Ag3PO4 and MoO3-x, there is efficient separation and utilization of photogenerated charge carriers. Owing to the rich presence of oxygen vacancies on the surface of MoO3-x, oxygen adsorption on the surface is enhanced. The as-prepared Ag3PO4/Ag/MoO3-x Z-scheme system shows outstanding photocatalytic activity and stability for the degradation of dyes (rhodamine B, methylene blue, as well as their mixture) and ciprofloxacin under visible light irradiation, displaying degradation rate that is 15.9, 3.4, 14.9 and 3.0 times that of MoO3-x, Ag3PO4, Ag/MoO3-x and Ag3PO4/MoO3-x, respectively. According to the results of trapping experiments, ·OH and ·O2− are the main active species, and a possible reaction mechanism has been proposed. © 2020 Elsevier B.V.

Keyword:

Ag3PO4/Ag/MoO3-x; Degradation; Oxygen vacancy; Z-scheme photocatalyst

Community:

  • [ 1 ] [Zhao, Z.-H.]State Key Laboratory of Chemo/Biosensing and Chemometrics, Provincial Hunan Key Laboratory for Cost-effective Utilization of Fossil Fuel Aimed at Reducing Carbon-dioxide Emissions, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Lushan South Road, Changsha, Hunan 410082, China
  • [ 2 ] [Wang, J.-B.]State Key Laboratory of Chemo/Biosensing and Chemometrics, Provincial Hunan Key Laboratory for Cost-effective Utilization of Fossil Fuel Aimed at Reducing Carbon-dioxide Emissions, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Lushan South Road, Changsha, Hunan 410082, China
  • [ 3 ] [Pan, J.-B.]State Key Laboratory of Chemo/Biosensing and Chemometrics, Provincial Hunan Key Laboratory for Cost-effective Utilization of Fossil Fuel Aimed at Reducing Carbon-dioxide Emissions, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Lushan South Road, Changsha, Hunan 410082, China
  • [ 4 ] [Tan, Y.-X.]State Key Laboratory of Chemo/Biosensing and Chemometrics, Provincial Hunan Key Laboratory for Cost-effective Utilization of Fossil Fuel Aimed at Reducing Carbon-dioxide Emissions, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Lushan South Road, Changsha, Hunan 410082, China
  • [ 5 ] [Chen, L.]State Key Laboratory of Chemo/Biosensing and Chemometrics, Provincial Hunan Key Laboratory for Cost-effective Utilization of Fossil Fuel Aimed at Reducing Carbon-dioxide Emissions, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Lushan South Road, Changsha, Hunan 410082, China
  • [ 6 ] [Guo, J.-K.]State Key Laboratory of Chemo/Biosensing and Chemometrics, Provincial Hunan Key Laboratory for Cost-effective Utilization of Fossil Fuel Aimed at Reducing Carbon-dioxide Emissions, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Lushan South Road, Changsha, Hunan 410082, China
  • [ 7 ] [Shen, S.]State Key Laboratory of Chemo/Biosensing and Chemometrics, Provincial Hunan Key Laboratory for Cost-effective Utilization of Fossil Fuel Aimed at Reducing Carbon-dioxide Emissions, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Lushan South Road, Changsha, Hunan 410082, China
  • [ 8 ] [Au, C.-T.]College of Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, China
  • [ 9 ] [Yin, S.-F.]State Key Laboratory of Chemo/Biosensing and Chemometrics, Provincial Hunan Key Laboratory for Cost-effective Utilization of Fossil Fuel Aimed at Reducing Carbon-dioxide Emissions, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Lushan South Road, Changsha, Hunan 410082, China

Reprint 's Address:

  • [Yin, S.-F.]State Key Laboratory of Chemo/Biosensing and Chemometrics, Provincial Hunan Key Laboratory for Cost-effective Utilization of Fossil Fuel Aimed at Reducing Carbon-dioxide Emissions, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, State Key Laboratory of Chemo/Biosensing and Chemometrics, Provincial Hunan Key Laboratory for Cost-effective Utilization of Fossil Fuel Aimed at Reducing Carbon-dioxide Emissions, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Lushan South Road, China

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Source :

Materials Chemistry and Physics

ISSN: 0254-0584

Year: 2020

Volume: 253

4 . 0 9 4

JCR@2020

4 . 3 0 0

JCR@2023

ESI HC Threshold:196

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count: 0

SCOPUS Cited Count: 19

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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