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author:

Ullah, A. (Ullah, A..) [1] | Khan, J. (Khan, J..) [2] | Sohail, M. (Sohail, M..) [3] | Hayat, A. (Hayat, A..) [4] | Zhao, T.K. (Zhao, T.K..) [5] | Ullah, B. (Ullah, B..) [6] | Khan, M. (Khan, M..) [7] | Uddin, I. (Uddin, I..) [8] | Ullah, S. (Ullah, S..) [9] | Ullah, R. (Ullah, R..) [10] | Rehman, A.U. (Rehman, A.U..) [11] | Khan, W.U. (Khan, W.U..) [12]

Indexed by:

Scopus

Abstract:

Utilization of solar heat radiation into chemical energy is attributed to semiconductor photocatalyst under sunlight perspective considered as a reversing inspired approach that exacerbates the environmental problems. Recently, our group indicates graphitic carbon nitride (g-CN) by a progressive molecular aggregation co-polymerization process that propagated with a nanoscopic organic conjugated heterocyclic monomer to enhance its photocatalytic activity. This work aims to present a facile induced co-condensation technique and used 2, 6-Furandicarboxylic acid (FA) monomer as demonstrator within g-CN that boosting the photocatalytic properties under solar energy driven caused the reduction of water. The as-prepared samples were demonstrated for various characterizations along with computational evaluation of pure and doped g-CN. The result signifying the integration of organic FA monomer in the triazine core shell of g-CN restoring a substantial delocalization in its π-conjugated system. Meanwhile, after this alternation, an identifiable undulation occurred in the surface area, electronic structure, calculated band gap, chemical composition analysis of g-CN, and also improved its electronic generation process under the visible light radiance. Besides, this unrepeatable integrity of FA co-monomer with ing-CN matrix considerably enhanced the photocatalytic activity toward Godspeed and as such, the superior photocatalyst CN/FA12.0 stimulated a tremendous photocatalytic activity of water reduction with 10.6 enhanced catalytic performances as a contrast of pristine sample respectively. © 2020 Elsevier B.V.

Keyword:

2, 6-Furandicarboxylic acid (FA) monomer; Co-polymerization; Graphitic carbon nitride (g-CN); Photocatalysis; Water reduction (HER)

Community:

  • [ 1 ] [Ullah, A.]School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an, Shaanxi 710072, China
  • [ 2 ] [Ullah, A.]NPU-NCP Joint International Research Center on Advance Nanomaterials and Defects Engineering, Northwestern Polytechnical University, Xi'an, Shaanxi 710072, China
  • [ 3 ] [Khan, J.]School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, China
  • [ 4 ] [Sohail, M.]Institute for Advanced Study, Shenzhen University, Shenzhen, 518060, China
  • [ 5 ] [Hayat, A.]College of Chemistry, Fuzhou University, Fuzhou, 350002, China
  • [ 6 ] [Zhao, T.K.]School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an, Shaanxi 710072, China
  • [ 7 ] [Zhao, T.K.]NPU-NCP Joint International Research Center on Advance Nanomaterials and Defects Engineering, Northwestern Polytechnical University, Xi'an, Shaanxi 710072, China
  • [ 8 ] [Ullah, B.]Institute for Advanced Study, Shenzhen University, Shenzhen, 518060, China
  • [ 9 ] [Khan, M.]School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an, Shaanxi 710072, China
  • [ 10 ] [Khan, M.]NPU-NCP Joint International Research Center on Advance Nanomaterials and Defects Engineering, Northwestern Polytechnical University, Xi'an, Shaanxi 710072, China
  • [ 11 ] [Uddin, I.]CAS Key Laboratory of Science and Technology on Applied Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian, 116023, China
  • [ 12 ] [Ullah, S.]Department of Chemistry, Anhui University, Hefei, 230601, China
  • [ 13 ] [Ullah, R.]Department of Chemistry, University of Turbat, Baluchistan, 92600, Pakistan
  • [ 14 ] [Rehman, A.U.]School of Chemical Engineering, Northwest University, Xi'an, China
  • [ 15 ] [Khan, W.U.]School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, China

Reprint 's Address:

  • [Hayat, A.]College of Chemistry, Fuzhou University, School of Materials Science and Engineering, Northwestern Polytechnical UniversityChina

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Source :

Journal of Photochemistry and Photobiology A: Chemistry

ISSN: 1010-6030

Year: 2020

Volume: 401

4 . 2 9 1

JCR@2020

4 . 1 0 0

JCR@2023

ESI HC Threshold:160

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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