One-dimensional　bunched　nanostructures　have　attracted　particular　research　interest　for　their　applications　in　energy-relate　fields.　However,　developing　a　reasonable　strategy　to　realize　such　unique　structure　design　still　remains　a　great　challenge.　Herein,　we　first　rationally　design　and　synthesize　a　distinct　one-dimensional　bunched　Ni-MoO2@Co-CoO-NC　composite　through　an　efficient　strategy　of　assembling　the　metal-organic　framework　(MOF)　and　transition　metal　oxide　(TMO),　in　which　the　MOF-derived　Co-CoO-NC　polyhedra　are　stringed　by　the　Ni-MoO2　nanowires.　The　synthesis　strategy　only　involves　the　effective　integration　of　the　ZIF-67　polyhedron　with　NiMoO4·xH2O　nanowires　via　solution　growth　at　room　temperature　followed　by　a　carbonation　treatment　under　an　Ar/H2　atmosphere.　Benefiting　from　the　favorable　morphological　and　structural　merits　as　well　as　the　synergistic　effects　from　different　components,　the　bunched　Ni-MoO2@Co-CoO-NC　composite　exhibits　a　remarkable　half-battery　performance　when　evaluated　as　the　anode　material　for　both　lithium/sodium-ion　batteries.　Furthermore,　electrode　kinetic　analyses　reveal　the　capacitive-controlled　behaviors　within　the　bunched　Ni-MoO2@Co-CoO-NC　composite.　Besides,　a　Ni-MoO2@Co-CoO-NC//LiFePO4　full　cell　is　fabricated,　which　can　deliver　a　high　energy　density　of　329　Wh　kg-1.　The　present　study　could　provide　an　insight　into　the　construction　of　TMOs　and　carbon　composites　with　one-dimensional　bunched　nanostructures.　Copyright　©　2020　American　Chemical　Society.