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author:

Chen, L. (Chen, L..) [1] | Zhu, D. (Zhu, D..) [2] | Li, J. (Li, J..) [3] | Wang, X. (Wang, X..) [4] | Zhu, J. (Zhu, J..) [5] | Francis, P.S. (Francis, P.S..) [6] | Zheng, Y. (Zheng, Y..) [7]

Indexed by:

Scopus

Abstract:

Modifying the structure of a photocatalyst to tailor its electronic and physicochemical properties is an effective approach for efficient photocatalysis. Herein, we demonstrate that co-doping non-metal (S) and metal (K) atoms into graphitic carbon nitride (g-C3N4) provides excellent visible-light photocatalytic hydrogen production activity of 8.78 mmol g−1 h−1, which is 98 times higher than that of pristine g-C3N4 (0.09 mmol g−1 h−1). The apparent quantum efficiency of the S+K-co-doped g-C3N4 reaches 70 % at 420 nm. This outstanding photocatalytic performance attributed to an increased specific surface area from 6.78 to 74.23 cm3 g−1, which reduced the recombination of photogenerated charge carriers and enhanced conductivity. Various characterizations are undertaken to elucidate the S+K-co-doped g-C3N4 photocatalytic mechanism. Our work not only demonstrates a facile, eco-friendly and scalable strategy for the synthesis of S+K-co-doped g-C3N4 photocatalysts, but also opens a new avenue for the design of co-doped photocatalysts. © 2020 Elsevier B.V.

Keyword:

Graphitic carbon nitride; Hydrogen evolution; Photocatalysis; Sulfur/potassium-co-doping

Community:

  • [ 1 ] [Chen, L.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, China
  • [ 2 ] [Zhu, D.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, China
  • [ 3 ] [Li, J.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, China
  • [ 4 ] [Wang, X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, China
  • [ 5 ] [Zhu, J.]Department of Chemistry – Ångstrom Laboratory, Uppsala University, Uppsala, SE-751 21, Sweden
  • [ 6 ] [Francis, P.S.]School of Life and Environmental Sciences, Faculty of Science, Engineering and Built Environment, Deakin University, Waurn PondsVictoria 3216, Australia
  • [ 7 ] [Zheng, Y.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350116, China

Reprint 's Address:

  • [Zhu, J.]Department of Chemistry – Ångstrom Laboratory, Uppsala UniversitySweden

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Source :

Applied Catalysis B: Environmental

ISSN: 0926-3373

Year: 2020

Volume: 273

1 9 . 5 0 3

JCR@2020

2 0 . 3 0 0

JCR@2023

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 144

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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