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author:

Xing, Y. (Xing, Y..) [1] | Ku, J. (Ku, J..) [2] | Fu, W. (Fu, W..) [3] | Wang, L. (Wang, L..) [4] | Chen, H. (Chen, H..) [5]

Indexed by:

Scopus

Abstract:

Oxygen evolution reaction (OER) remains the bottleneck of many energy transformation and storage technologies due to the sluggish kinetics. Transition-metal (TM) hydroxide nanosheets with high-valent TM ions possess high intrinsic catalytic activity toward OER. Herein, by taking advantage of the inductive effect, this work presents a facile and universal strategy to fabricate atomic iridium (Ir) incorporated TM hydroxide nanosheets as highly active OER electrocatalysts. As a representative, the fabricated Ir-Ni(OH)2 (4 wt% Ir) exhibits remarkable OER performance with a low overpotential (235 mV at 10 mA cm−2), a small Tafel slope (58.4 mV dec−1), and excellent durability (60 h) in alkaline solution, significantly outperforming the benchmark IrO2 and Ni(OH)2. Mechanism studies unveil that the inductive effect between Ni and Ir endows Ni(OH)2 with high-valent Ni species, which facilitate the adsorption of nucleophilic intermediates and boost the OER activity and long-term stability of Ir-Ni(OH)2. More importantly, the reported strategy could be extended to synthesize other monometallic/bimetallic TM hydroxide nanosheets (Co, CoMn) as highly efficient OER electrocatalysts. This work should pave a universal and promising avenue to rationally design and controllably synthesize efficient yet robust OER electrocatalysts in energy-related fields. © 2020 Elsevier B.V.

Keyword:

Atomic Ir incorporation; Electrocatalysts; Inductive effect; Nanosheets; Oxygen evolution reaction; Transition-metal hydroxides

Community:

  • [ 1 ] [Xing, Y.]Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, 230026, China
  • [ 2 ] [Ku, J.]School of Zijin Mining, Fuzhou University, Fuzhou, 350108, China
  • [ 3 ] [Fu, W.]School of Chemical Engineering, The University of Queensland, Brisbane, Qld 4072, Australia
  • [ 4 ] [Wang, L.]School of Chemical Engineering, The University of Queensland, Brisbane, Qld 4072, Australia
  • [ 5 ] [Chen, H.]Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei, 230026, China

Reprint 's Address:

  • [Wang, L.]School of Chemical Engineering, The University of QueenslandAustralia

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Source :

Chemical Engineering Journal

ISSN: 1385-8947

Year: 2020

Volume: 395

1 3 . 2 7 3

JCR@2020

1 3 . 4 0 0

JCR@2023

ESI HC Threshold:132

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 57

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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