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author:

Liu, B. (Liu, B..) [1] | Lei, D. (Lei, D..) [2] | Wang, J. (Wang, J..) [3] | Zhang, Q. (Zhang, Q..) [4] | Zhang, Y. (Zhang, Y..) [5] | He, W. (He, W..) [6] | Zheng, H. (Zheng, H..) [7] | Sa, B. (Sa, B..) [8] | Xie, Q. (Xie, Q..) [9] | Peng, D.-L. (Peng, D.-L..) [10] | Qu, B. (Qu, B..) [11]

Indexed by:

Scopus CSCD

Abstract:

Sodium metal batteries are arousing extensive interest owing to their high energy density, low cost and wide resource. However, the practical development of sodium metal batteries is inherently plagued by the severe volume expansion and the dendrite growth of sodium metal anode during long cycles under high current density. Herein, a simple electrospinning method is applied to construct the uniformly nitrogen-doped porous carbon fiber skeleton and used as three-dimensional (3D) current collector for sodium metal anode, which has high specific surface area (1,098 m2/g) and strong binding to sodium metal. As a result, nitrogen-doped carbon fiber current collector shows a low sodium deposition overpotential and a highly stable cyclability for 3,500 h with a high coulombic effciency of 99.9% at 2 mA/cm2 and 2 mAh/cm2. Moreover, the full cells using carbon coated sodium vanadium phosphate as cathode and sodium pre-plated nitrogen-doped carbon fiber skeleton as hybrid anode can stably cycle for 300 times. These results illustrate an effective strategy to construct a 3D uniformly nitrogen-doped carbon skeleton based sodium metal hybrid anode without the formation of dendrites, which provide a prospect for further development and research of high performance sodium metal batteries. [Figure not available: see fulltext.]. © 2020, Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature.

Keyword:

nitrogen-doping; porous carbon skeleton; sodium affinity; sodium metal anode; ultra-stable cyclability

Community:

  • [ 1 ] [Liu, B.]Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 2 ] [Lei, D.]State Key Laboratory of Optoelectronic Materials and Technologies, School of Materials Science and Engineering, Sun Yat-Sen (Zhongshan) University, Guangzhou, 510275, China
  • [ 3 ] [Wang, J.]Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 4 ] [Zhang, Q.]Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 5 ] [Zhang, Y.]Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 6 ] [He, W.]Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 7 ] [Zheng, H.]Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 8 ] [Sa, B.]Multiscale Computational Materials Facility, College of Materials Science and Engineering, Fuzhou University, Fuzhou, 350100, China
  • [ 9 ] [Xie, Q.]Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 10 ] [Peng, D.-L.]Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, College of Materials, Xiamen University, Xiamen, 361005, China
  • [ 11 ] [Qu, B.]Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, College of Materials, Xiamen University, Xiamen, 361005, China

Reprint 's Address:

  • [Qu, B.]Pen-Tung Sah Institute of Micro-Nano Science and Technology, Fujian Key Laboratory of Materials Genome, College of Materials, Xiamen UniversityChina

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Source :

Nano Research

ISSN: 1998-0124

Year: 2020

Issue: 8

Volume: 13

Page: 2136-2142

8 . 8 9 7

JCR@2020

9 . 6 0 0

JCR@2023

ESI HC Threshold:115

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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