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author:

Zhong, H. (Zhong, H..) [1] | Sa, R. (Sa, R..) [2] | Lv, H. (Lv, H..) [3] | Yang, S. (Yang, S..) [4] | Yuan, D. (Yuan, D..) [5] | Wang, X. (Wang, X..) [6] | Wang, R. (Wang, R..) [7]

Indexed by:

Scopus

Abstract:

The visible-light-driven photocatalytic CO2 reduction is one appealing approach to simultaneously mitigate the energy crisis and environmental issues. It is highly desirable but challenging to selectively and efficiently convert CO2 into desirable products. Herein, a covalent organic framework hosting metalloporphyrin-based carbon dots (M-PCD@TD-COF, M = Ni, Co, and Fe) is first presented, which serves as heterogeneous catalysts for CO2 photoreduction. M-PCD@TD-COF not only enriches available COF-based catalytic materials, but also provides suitable environment for CO2 adsorption and activation on metalloporphyrin-based carbon dots. The advantages of the host environment in COFs are highlighted by the satisfactory catalytic activity and remarkable selectivity of CO2-to-CO conversion over H2 generation up to 98%. The photocatalytic system is effective for both pure CO2 and the simulated flue gas. This work provides new protocols for the rational design of COF-based heterogeneous catalysts for selective CO2 photoreduction. © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Keyword:

carbon dots; CO2 reduction; covalent organic frameworks; photocatalysis; porous materials

Community:

  • [ 1 ] [Zhong, H.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
  • [ 2 ] [Sa, R.]Institute of Oceanography, Ocean College, Minjiang University, Fuzhou, Fujian 350108, China
  • [ 3 ] [Lv, H.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
  • [ 4 ] [Yang, S.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
  • [ 5 ] [Yuan, D.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
  • [ 6 ] [Wang, X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 7 ] [Wang, R.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

Reprint 's Address:

  • [Wang, R.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of SciencesChina

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Source :

Advanced Functional Materials

ISSN: 1616-301X

Year: 2020

Issue: 35

Volume: 30

1 8 . 8 0 8

JCR@2020

1 8 . 5 0 0

JCR@2023

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 141

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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