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author:

Kahrizi, M. (Kahrizi, M..) [1] | Lin, J. (Lin, J..) [2] | Ji, G. (Ji, G..) [3] | Kong, L. (Kong, L..) [4] | Song, C. (Song, C..) [5] | Dumée, L.F. (Dumée, L.F..) [6] | Sahebi, S. (Sahebi, S..) [7] | Zhao, S. (Zhao, S..) [8]

Indexed by:

Scopus

Abstract:

A 2D finite element model was developed to describe the forward osmosis (FO) process under steady-state conditions. Two approaches are applied to study forward water and reverse salt fluxes. In the first approach, the mathematical equations are formulated based on the bulk concentration differences between the feed and the draw solutions. Transfer resistances arising from internal concentration polarization, external concentration polarization and reverse salt flux are considered. The second approach is based on a complete computational fluid dynamic (CFD) model, both the constrictivity factor and the sorption coefficient are considered to enhance the accuracy of prediction. The CFD model provides a more realistic representation of the FO process than the first simple approach. Our CFD model shows that the concentration profile within the membrane support layer is a result of the coupled interaction between the dilutive internal concentration polarization and the reverse solute diffusion from the draw. Increasing porosity or decreasing tortuosity is not always desirable since it will also increase reverse salt flux. Forward water and reverse salt fluxes are independent on tortuosity or porosity alone, but dependent on their ratios. This work offers significant insights into developing high performance FO membranes with suitable porosity and tortuosity, thereby reducing internal concentration polarization and reverse salt diffusion. © 2020 Elsevier B.V.

Keyword:

Computational fluid dynamics; Concentration polarization; Forward osmosis; Membrane porosity; Reverse salt flux; Water flux

Community:

  • [ 1 ] [Kahrizi, M.]College of Environmental Science and Engineering, Dalian Maritime University, Dalian, 116026, China
  • [ 2 ] [Lin, J.]School of Environment and Resources, Fuzhou University, Fuzhou, 350116, China
  • [ 3 ] [Ji, G.]School of Environmental Science and Technology, Dalian University of Technology, Dalian, 116024, China
  • [ 4 ] [Kong, L.]Deakin University, Geelong, Institute for Frontier MaterialsVIC 3216, Australia
  • [ 5 ] [Song, C.]College of Environmental Science and Engineering, Dalian Maritime University, Dalian, 116026, China
  • [ 6 ] [Dumée, L.F.]Deakin University, Geelong, Institute for Frontier MaterialsVIC 3216, Australia
  • [ 7 ] [Sahebi, S.]Department for Management of Science and Technology Development, Ton Duc Thang University, Ho Chi Minh City, Viet Nam
  • [ 8 ] [Zhao, S.]College of Environmental Science and Engineering, Dalian Maritime University, Dalian, 116026, China
  • [ 9 ] [Zhao, S.]Deakin University, Geelong, Institute for Frontier MaterialsVIC 3216, Australia

Reprint 's Address:

  • [Zhao, S.]College of Environmental Science and Engineering, Dalian Maritime UniversityChina

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Source :

Separation and Purification Technology

ISSN: 1383-5866

Year: 2020

Volume: 241

7 . 3 1 2

JCR@2020

8 . 2 0 0

JCR@2023

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 37

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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