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author:

Zhang, J. (Zhang, J..) [1] | Lai, R.-D. (Lai, R.-D..) [2] | Wu, Y.-L. (Wu, Y.-L..) [3] | Zhu, Z.-K. (Zhu, Z.-K..) [4] | Sun, Y.-Q. (Sun, Y.-Q..) [5] | Zeng, Q.-X. (Zeng, Q.-X..) [6] | Li, X.-X. (Li, X.-X..) [7] | Zheng, S.-T. (Zheng, S.-T..) [8]

Indexed by:

Scopus

Abstract:

In this work, two rare high-dimensional polyoxoniobates with formulas of H9[Cu(en)(H2O)2][Cu(en)2]8[Dy(H2O)4]3[Nb24-O69(H2O)3]2 ⋅ 36H2O (1) and H9K[Cu(en)2(H2O)]5[Cu(en)2]4-[Eu(H2O)4]3[Nb24O69(H2O)3]2 ⋅ 2en ⋅ 45H2O (2) have been obtained under hydrothermal conditions. These extended materials are constructed from lanthanide-incorporated triangular-prism-like polyoxoniobate secondary building units (SBUs) {[Ln(H2O)4]3[Nb24O69(H2O)3]2} (Ln=Dy, Eu). 1 and 2 represent the first examples of high-dimensional polyoxometalate materials based on such lanthanide-incorporated triangular-prism-like polyoxoniobate SBUs. Furthermore, the proton conduction property and the luminescent emission of these materials were evaluated. © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Keyword:

High-dimensional material; Luminescent property; Polyoxometalate; Polyoxoniobate; Proton conduction; Rare earth

Community:

  • [ 1 ] [Zhang, J.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 2 ] [Lai, R.-D.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 3 ] [Wu, Y.-L.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 4 ] [Zhu, Z.-K.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 5 ] [Sun, Y.-Q.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 6 ] [Zeng, Q.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 7 ] [Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China
  • [ 8 ] [Li, X.-X.]State Key Laboratory of Structural chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
  • [ 9 ] [Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350108, China

Reprint 's Address:

  • [Zeng, Q.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

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Source :

Chemistry - An Asian Journal

ISSN: 1861-4728

Year: 2020

Issue: 10

Volume: 15

Page: 1574-1579

4 . 5 6 8

JCR@2020

3 . 5 0 0

JCR@2023

ESI HC Threshold:160

JCR Journal Grade:2

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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