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Abstract:
In this work, two rare high-dimensional polyoxoniobates with formulas of H9[Cu(en)(H2O)2][Cu(en)2]8[Dy(H2O)4]3[Nb24-O69(H2O)3]2 ⋅ 36H2O (1) and H9K[Cu(en)2(H2O)]5[Cu(en)2]4-[Eu(H2O)4]3[Nb24O69(H2O)3]2 ⋅ 2en ⋅ 45H2O (2) have been obtained under hydrothermal conditions. These extended materials are constructed from lanthanide-incorporated triangular-prism-like polyoxoniobate secondary building units (SBUs) {[Ln(H2O)4]3[Nb24O69(H2O)3]2} (Ln=Dy, Eu). 1 and 2 represent the first examples of high-dimensional polyoxometalate materials based on such lanthanide-incorporated triangular-prism-like polyoxoniobate SBUs. Furthermore, the proton conduction property and the luminescent emission of these materials were evaluated. © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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Source :
Chemistry - An Asian Journal
ISSN: 1861-4728
Year: 2020
Issue: 10
Volume: 15
Page: 1574-1579
4 . 5 6 8
JCR@2020
3 . 5 0 0
JCR@2023
ESI HC Threshold:160
JCR Journal Grade:2
CAS Journal Grade:3
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1
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