Redox Neutral Radical-Relay Cobalt Catalysis toward C-H Fluorination and Amination - Details

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Abstract：

A　redox　neutral　radical-relay　cobalt-catalyzed　intramolecular　C-H　fluorination　of　N-fluoroamides　featuring　the　in　situ　formed　cobalt　fluorides　as　the　latent　radical　fluorinating　agents　is　reported.　Moreover,　the　reactivity　of　such　a　cobalt　catalysis　could　be　diverted　from　C-H　fluorination　to　amination　by　engineering　substrates＇　conformational　flexibility.　Preliminary　mechanistic　studies　(UV-vis　spectroscopy,　cyclic　voltammetry　studies　and　DFT　calculations,　etc.)　support　the　reaction　proceeding　a　redox　neutral　radical-relay　mechanism.　©　2020　American　Chemical　Society.

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[ 1 ] [Guo, P.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Li, Y.]State Key Lab. of Phys. Chem. of Solid Surf. and Collab. Innov. Ctr. of Chem. for Ener. Mat. (IChEM), Fujian Prov. Key Laboratory of Theoretical and Computational Chemistry and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China
[ 3 ] [Zhang, X.-G.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 4 ] [Han, J.-F.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 5 ] [Yu, Y.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 6 ] [Zhu, J.]State Key Lab. of Phys. Chem. of Solid Surf. and Collab. Innov. Ctr. of Chem. for Ener. Mat. (IChEM), Fujian Prov. Key Laboratory of Theoretical and Computational Chemistry and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China
[ 7 ] [Ye, K.-Y.]Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou, 350108, China

Reprint 's Address：

[Zhu, J.]State Key Lab. of Phys. Chem. of Solid Surf. and Collab. Innov. Ctr. of Chem. for Ener. Mat. (IChEM), Fujian Prov. Key Laboratory of Theoretical and Computational Chemistry and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen UniversityChina

Email：

jun.zhu@xmu.edu.cn

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Source ：

Organic Letters

ISSN： 1523-7060

Year： 2020

Issue： 9

Volume： 22

Page： 3601-3606

6 . 0 0 5

JCR@2020

4 . 9 0 0

JCR@2023

ESI HC Threshold：160

JCR Journal Grade：1

CAS Journal Grade：1

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 1

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