Indexed by:
Abstract:
Earth-abundant transition metal cocatalysts are promising rare and noble metal alternatives for efficient photocatalytic hydrogen evolution. Herein, a novel composite of ZIF-67 derived CoOx nanodots confined in a N, S co-doped graphitic nanosheet co-catalyst (CoOx@N, S-C) was successfully constructed via a one pot carbonization process. Through loading onto photosensitizer of CdS nanorods, the obtained CoOx@N, S-C/CdS composite exhibited an unprecedented H2 production rate of 40.1 mmol g-1 h-1, which is 57, 20 and 1.7 times higher than that of CdS, N, S-C/CdS and CoOx/CdS, respectively. It was demonstrated that the excellent photocatalytic H2 production performance arises from the synergetic effect between the confined ultrafine CoOx nanodots and N, S heteroatom co-doped graphitic carbon. This work shows considerable improvements over MOF derived materials as non-noble cocatalysts and provides significant motivation for new photocatalyst development for improving the conversion efficiency of solar energy to chemical fuels. © 2020 The Royal Society of Chemistry.
Keyword:
Reprint 's Address:
Email:
Source :
Sustainable Energy and Fuels
ISSN: 2398-4902
Year: 2020
Issue: 4
Volume: 4
Page: 1954-1962
6 . 3 6 7
JCR@2020
5 . 0 0 0
JCR@2023
ESI HC Threshold:196
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
SCOPUS Cited Count: 12
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
Affiliated Colleges: