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author:

Wang, J. (Wang, J..) [1] | Xu, Q. (Xu, Q..) [2] | Liu, M. (Liu, M..) [3] | Wang, K. (Wang, K..) [4] | Wang, Z. (Wang, Z..) [5] | Qu, P. (Qu, P..) [6]

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Scopus

Abstract:

Earth-abundant transition metal cocatalysts are promising rare and noble metal alternatives for efficient photocatalytic hydrogen evolution. Herein, a novel composite of ZIF-67 derived CoOx nanodots confined in a N, S co-doped graphitic nanosheet co-catalyst (CoOx@N, S-C) was successfully constructed via a one pot carbonization process. Through loading onto photosensitizer of CdS nanorods, the obtained CoOx@N, S-C/CdS composite exhibited an unprecedented H2 production rate of 40.1 mmol g-1 h-1, which is 57, 20 and 1.7 times higher than that of CdS, N, S-C/CdS and CoOx/CdS, respectively. It was demonstrated that the excellent photocatalytic H2 production performance arises from the synergetic effect between the confined ultrafine CoOx nanodots and N, S heteroatom co-doped graphitic carbon. This work shows considerable improvements over MOF derived materials as non-noble cocatalysts and provides significant motivation for new photocatalyst development for improving the conversion efficiency of solar energy to chemical fuels. © 2020 The Royal Society of Chemistry.

Keyword:

Community:

  • [ 1 ] [Wang, J.]Henan Engineering Center of New Energy Battery Materials, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu, 476000, China
  • [ 2 ] [Wang, J.]College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001, China
  • [ 3 ] [Xu, Q.]State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, 030001, China
  • [ 4 ] [Liu, M.]College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001, China
  • [ 5 ] [Wang, K.]Henan Engineering Center of New Energy Battery Materials, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu, 476000, China
  • [ 6 ] [Wang, Z.]State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, 030001, China
  • [ 7 ] [Wang, Z.]State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350116, China
  • [ 8 ] [Qu, P.]Henan Engineering Center of New Energy Battery Materials, College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu, 476000, China

Reprint 's Address:

  • [Wang, Z.]State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of SciencesChina

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Source :

Sustainable Energy and Fuels

ISSN: 2398-4902

Year: 2020

Issue: 4

Volume: 4

Page: 1954-1962

6 . 3 6 7

JCR@2020

5 . 0 0 0

JCR@2023

ESI HC Threshold:196

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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