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author:

Wang, R. (Wang, R..) [1] | Zhang, T. (Zhang, T..) [2] | Zhang, Q. (Zhang, Q..) [3] | Zheng, M. (Zheng, M..) [4] | Xu, K. (Xu, K..) [5] | Yan, W. (Yan, W..) [6]

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Scopus

Abstract:

With the development of the times, the energy density of cathodes can no longer meet the requirement of the society, which has greatly limited the commercialization process of Ni-rich cathodes. Doping combined with coating is a perfect approach to improve the performance of Ni-rich cathodes. In this paper, La was used as a modified element to realize doping in the layered host structure as well as La2O3 coating on the surface. To further enhance the interface stability of LiNi0.8Co0.1Mn0.1O2, F was also employed to modify the surface, so as to change the coating layer from oxide (La2O3) to fluoride (LaF3), which further improved the surface stability. Additionally, a series of testing instruments, including XRD, EDS mapping, and HRTEM, were employed, which suggested that a small amount of La was introduced into the host structure as a pillar to the stable layered structure, and there was an uniform LaF3 coating layer covered on the Ni-rich cathodes. As a result, the electrochemical performance of the cathodes was greatly improved, with the capacity retention of 86.63% and 80.79% after 200 cycles at 1 C rate and 300 cycles at 8 C rate, respectively; besides, the kinetics of lithium diffusion was also improved. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.

Keyword:

Cathode; Coating; Doping; LiNi0.8Co0.1Mn0.1O2; Ni-rich

Community:

  • [ 1 ] [Wang, R.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Zhang, T.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 3 ] [Zhang, Q.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Zheng, M.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [Xu, K.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 6 ] [Yan, W.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address:

  • [Wang, R.]College of Chemistry, Fuzhou UniversityChina

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Source :

Ionics

ISSN: 0947-7047

Year: 2020

Issue: 3

Volume: 26

Page: 1165-1171

2 . 8 1 7

JCR@2020

2 . 4 0 0

JCR@2023

ESI HC Threshold:115

JCR Journal Grade:3

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 12

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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