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author:

Yang, W. (Yang, W..) [1] | Zhang, G. (Zhang, G..) [2] | Ni, J. (Ni, J..) [3] | Lin, Z. (Lin, Z..) [4]

Indexed by:

Scopus

Abstract:

Fluorescent nanoparticles were prepared by encapsulating carbon dots (CDs) within silica spheres and then modifying these spheres with amino groups (CD@SiO2-NH2). On the basis of the silver mirror reaction, Ag+ assembled on the surface of CD@SiO2-NH2 is reduced to silver nanoparticles (AgNPs) by formaldehyde. The in-situ grown AgNPs cause a visually distinguishable fluorescence enhancement. This metal-enhanced effect was investigated by transmission electron microscopy and spectroscopic characterization, and the relevant conditions were optimized. CD@SiO2-NH2-Ag+ fluorescent probes were loaded onto nano-sponge pieces for the analysis of formaldehyde gas. The blue fluorescence emission (peaking at 466 nm) in response to formaldehyde is greatly enhanced (up to 5.2 times) over other species. There is a linear relationship between the fluorescence enhancement and formaldehyde gas concentration in the range of 10 ppb to 1 ppm, and the detection limit is 3 ppb. The fluorimetric assay needs 30 min for the reaction, and the fluorescent nano-sponge pieces are disposable. [Figure not available: see fulltext.] © 2020, Springer-Verlag GmbH Austria, part of Springer Nature.

Keyword:

Environmental pollutants; Fluorescent nanoparticles; Gas determination; Metal-enhanced fluorescence; Nano-sponge; Silica spheres; Silver mirror reaction; Visual detection

Community:

  • [ 1 ] [Yang, W.]Fujian Provincial Key Laboratory of Pollution Monitoring and Control, Fujian Provincial Key Laboratory of Modern Analytical Science and Separation Technology, College of Chemistry and Environment, Minnan Normal University, Zhangzhou, 363000, China
  • [ 2 ] [Yang, W.]MOE Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 3 ] [Zhang, G.]Fujian Provincial Collaborative Innovation Institute of Food Industry Technology Zhangzhou Institute of Technology, Zhangzhou, 363000, China
  • [ 4 ] [Ni, J.]Fujian Provincial Key Laboratory of Pollution Monitoring and Control, Fujian Provincial Key Laboratory of Modern Analytical Science and Separation Technology, College of Chemistry and Environment, Minnan Normal University, Zhangzhou, 363000, China
  • [ 5 ] [Lin, Z.]MOE Key Laboratory for Analytical Science of Food Safety and Biology, Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address:

  • [Ni, J.]Fujian Provincial Key Laboratory of Pollution Monitoring and Control, Fujian Provincial Key Laboratory of Modern Analytical Science and Separation Technology, College of Chemistry and Environment, Minnan Normal UniversityChina

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Source :

Microchimica Acta

ISSN: 0026-3672

Year: 2020

Issue: 2

Volume: 187

5 . 8 3 3

JCR@2020

5 . 4 0 0

JCR@2023

ESI HC Threshold:160

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 19

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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