Synthesis, crystal structure and magnetic property of 30-membered decanuclear manganese metallacrown with N-cyclohexanoylsalicylhydrazide ligand - Details

author：

Du, K. (Du, K..) ^[1] | Liu, S.-X. (Liu, S.-X..) ^[2] | Lin, B. (Lin, B..) ^[3]

Indexed by：

Scopus

Abstract：

Pentadentate　ligand,　N-cyclohexanoylsalicylhydrazide　(H3chxshz)　(1),　and　its　self-assembled　30-metallacrown-10,　[Mn10(C14H15N2O3)10(CH3OH)10]·16CH3OH　(2),　have　been　synthesized.　Ten　manganese　(III)　ions　and　ten　deprotonated　ligands　(chxshz3−)　construct　a　30-membered　ring　based　on　the　M-N-N-M　linkage　in　the　novel　decanuclear　manganese(III)　metallamacrocycle　2.　The　chiralities　of　Mn　atoms　in　the　diaza-bridged　ring　are　in　alternating　Λ　and　Δ　configurations.　The　magnetic　property　of　the　title　30-metallacrown-10　shows　a　weak　antiferromagnetic　exchange　interaction　with　an　observed　μeff　of　14.93　μB　at　300　K.　©　2019　Elsevier　B.V.

Keyword：

Crystal structure; Manganese complex; Metallacrown; Metallamacrocycle

Community：

[ 1 ] [Du, K.]College of Materials Science and Engineering, Huaqiao University, Xiamen, 361021, China
[ 2 ] [Liu, S.-X.]Central Laboratory, Fuzhou University, Fuzhou, 350002, China
[ 3 ] [Lin, B.]College of Materials Science and Engineering, Huaqiao University, Xiamen, 361021, China

Reprint 's Address：

[Du, K.]College of Materials Science and Engineering, Huaqiao UniversityChina

Email：

dukang@hqu.edu.cn

Show more details

Related Keywords：

Source ：

Inorganic Chemistry Communications

ISSN： 1387-7003

Year： 2020

Volume： 111

2 . 4 9 5

JCR@2020

4 . 4 0 0

JCR@2023

ESI HC Threshold：160

JCR Journal Grade：2

CAS Journal Grade：4

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS

Type
Departments

All Years Choose Year From to