Pulse　electric　field　induced　electron　emission　from　the　ferroelectric　polymer　has　been　investigated.　Electron　emission　of　unpoled　and　poled　poly(vinylidene　fluoride)　thin　films　prepared　by　spin　coating　was　measured　under　increasing　driving　field　with　fixed　pulse-exited　frequency.　The　results　showed　that　me　emission　current　from　poled　polymer　thin　film　is　attributed　to　its　polarization,　including　the　polarization　reversal　in　the　crystalline　phase　or　amorphous　phase,　and　the　emission　of　excess　charges　in　the　Maxwell-Wagner　interface.　And　besides,　it　is　found　that　the　charges　frozen　and　injected　in　the　Maxwell-Wagner　interface　under　an　appropriate　driving　pulse　field　played　an　important　role　of　electron　emission　for　unpoled　thin　film　sample.　Copyright　©　Taylor　&　Francis　Group,　LLC.