The　influence　of　heat　treatment　on　microstructure　of　Ni-P-PTFE　electroless　composite　coating　was　analyzed　with　SEM.XRD　and　DSC,　and　wear　resistance　of　the　coating　were　studied.　The　results　show　that　the　volatilization　of　the　PTFE　takes　place　mainly　in　the　surface　layer　and　the　change　of　interior　PTFE　content　is　small　after　heat　treatment　at　400　°c　for　1　h.　The　coating　as　deposited　presents　amorphous,　crystallization　completes　after　heat　treatment　at　400　°　for　1　h,　and　Ni,　Ni3P　phases　are　formed.　The　crystallization　onset　temperature　and　the　peak　temperature　of　the　Ni-P-PrFE　composite　coating　are　higher　than　those　of　the　Ni-P　coating,　and　the　crystallization　activation　energy　of　Ni-P-PTFE　composite　coating　is　235　kj/mol,　which　is　comparative　with　that　of　Ni-P　coating.　The　friction　coefficient　and　the　wear　loss　are　the　least　when　the　adding　amount　of　PTFE　is　8　mL/L　Compared　with　the　Ni-P　coating,　Ni-P-PTFE　composite　coating　shows　better　wear　resistance　and　the　lower　friction　coefficient　under　different　heat　treating　temperatuer.