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Abstract:
Transport of Cu2+ through supported liquid membrane (SLM) using Celgard 2500 as support and LIX984 dissolved in kerosene as carrier was studied. Based on double membrane theory, a transport rate model was used to describe the transport process under steady state. When the acid concentration in stripping solution was over 2 mol/L, the mass transfer resistance of stripping side could be neglected. The variation of separated mass transfer coefficient, km, in the membrane could be used to describe the degradation of SLM. During the process of mass transfer, km increased at the beginning and then decreased gradually. Moreover, the carrier was more inclined to lose than the kerosene diluent. The influences of operation conditions on the mass transfer and membrane liquid loss were also investigated. The results showed that the initial mass transfer flux J0 increased with the increase of initial concentrations of carrier and Cu2+, and initial pH value in feed solution. The loss of membrane liquid increased with the increase of carrier concentration in membrane liquid and the decrease of copper concentration in feed solution. However, the pH value had little influence on the loss of membrane liquid.
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The Chinese Journal of Process Engineering
ISSN: 1009-606X
CN: 11-4541/TQ
Year: 2009
Issue: 1
Volume: 9
Page: 1-6
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0
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