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author:

Yang, G.-D. (Yang, G.-D..) [1] | Zheng, J.-P. (Zheng, J.-P..) [2] | Huang, H.-X. (Huang, H.-X..) [3] | Qi, G.-M. (Qi, G.-M..) [4] | Xu, J.-H. (Xu, J.-H..) [5] | Fu, F.-F. (Fu, F.-F..) [6]

Indexed by:

Scopus PKU CSCD

Abstract:

A capillary zone electrophoresis-ultraviolet detection (CZE-UV) method for the analysis of five arsenic compounds, As( m ) , dimethylarsinic acid (DMA), p-aminophenyl arsenic acid(p-As) , monomethyl-arsonic acid(MMA) and As( V ) , in sea foods was described. The optimum conditions of CE determination including detection wavelength, chemical component of buffer solution, pH, buffer concentration, separation voltage and injection time were studied in detail. The results showed that five species of arsenic were base line separated within 11 min under optimum conditions. The relative standard deviations of migration times and peak areas were 0. 5% -1.5% and1.7% -3.4%, respectively, and the detection limits were 0.004-0.30 mg/L. The method was successfully used to determine different species of arsenic in dried shrimps with recoveries of 93% - 106%.

Keyword:

Arsenic; Capillary zone electrophoresis; Shrimp; Speciation analysis

Community:

  • [ 1 ] [Yang, G.-D.]Key Laboratory of Analysis and Detection for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou 350002, China
  • [ 2 ] [Yang, G.-D.]College of Life Sciences, Fujian Agriculture and Forestrj University, Fuzhou 350002, China
  • [ 3 ] [Zheng, J.-P.]Key Laboratory of Analysis and Detection for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou 350002, China
  • [ 4 ] [Huang, H.-X.]Fujian Provincial Central Inspection Institute, Fuzhou 350002, China
  • [ 5 ] [Qi, G.-M.]Key Laboratory of Analysis and Detection for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou 350002, China
  • [ 6 ] [Xu, J.-H.]Key Laboratory of Analysis and Detection for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou 350002, China
  • [ 7 ] [Fu, F.-F.]Key Laboratory of Analysis and Detection for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou 350002, China

Reprint 's Address:

  • [Fu, F.-F.]Key Laboratory of Analysis and Detection for Food Safety, Department of Chemistry, Fuzhou University, Fuzhou 350002, China

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Source :

Chinese Journal of Analytical Chemistry

ISSN: 0253-3820

CN: 22-1125/O6

Year: 2009

Issue: 4

Volume: 37

Page: 532-536

0 . 7 9

JCR@2009

1 . 2 0 0

JCR@2023

JCR Journal Grade:3

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 15

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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