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Microwave dielectric ceramics of CaLa4Ti4O15 were prepared by the solid-state reaction method. The influence of the calcining temperature on the sintering behavior and microwave dielectric properties was investigated. For the specimen calcined at 1200°C, CaTiO3, La2Ti2O7 and La2TiO5 mixed phases were observed in addition to the CaLa4Ti4O15 phase, while the hexagonal perovskite single phase was achieved for the CaLa4Ti4O15 powders calcined at 1300°C or 1400°C. CaLa4Ti4O15 ceramics were sintered well with high relative density of about 97%. On the other hand, the ceramics had a high mechanical quality factor plus resonant frequency (Q × f) value and near zero temperature coefficient of resonant frequency (τf). The CaLa4Ti4O15 ceramics sintered at 1550°C exhibited excellent microwave dielectric properties as follows: relative dielectric constant εr =45.1, Q × f =46 087 GHz, τf = -14.1 × 10-6/°C and εr =45.9, Q × f =48 871 GHz, τf = -14.4 × 10-6/°C for the specimens calcined at 1200°C and 1300°C, respectively.
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Journal of the Chinese Ceramic Society
ISSN: 0454-5648
Year: 2008
Issue: 12
Volume: 36
Page: 1695-1699
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WoS CC Cited Count: 0
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ESI Highly Cited Papers on the List: 0 Unfold All
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Chinese Cited Count:
30 Days PV: 5
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