Synthesis, structure and temperature-depended 2D IR correlation spectroscopy of an organo-bismuth benzoate with 1,10-phenanthroline - Details

author：

Sun, Y.-Q. (Sun, Y.-Q..) ^[1] | Zhong, J.-C. (Zhong, J.-C..) ^[2] | Liu, L.-H. (Liu, L.-H..) ^[3] | Qiu, X.-T. (Qiu, X.-T..) ^[4] | Chen, Y.-P. (Chen, Y.-P..) ^[5]

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Abstract：

An　organo-bismuth　benzoate　with　phen　as　auxiliary　ligand,　[Bi(phen)(C6H5COO)(C6H4COO)]　(1)　(phen = 1,10-phenanthroline)　has　been　hydrothermally　synthesized　from　bismuth　nitrate,　2-mercaptonbenzoic　acid　with　phen　as　auxiliary　ligand　and　characterized　by　single-crystal　X-ray　diffraction,　elemental　analyses,　PXRD,　IR　spectra,　TG　analyses,　temperature-depended　2D-IR　COS　(two-dimensional　infrared　correlation　spectroscopy).　Interestingly,　benzoate　anions　in　1　came　from　the　desulfuration　reaction　of　2-mercaptonbenzoic　acid　under　hydrothermal　condition.　Compound　1　is　a　discrete　organo-bismuth　compound　with　benzoate　and　phen　ligands.　The　offset　face-to-face　π-π　stacking　interactions　and　C–H⋯O　hydrogen　bonds　link　the　isolate　complex　into　a　3D　supramolecular　network.　The　temperature-depended　2D-IR　COS　indicates　that　the　stretching　vibrations　of　C[dbnd]C/C[dbnd]N　of　aromatic　rings　and　C[dbnd]O　bonds　are　sensitive　to　the　temperature　change.　©　2016　Elsevier　B.V.

Keyword：

2D IR correlation spectroscopy; Bismuth benzoate; In situ reaction of 2-mercaptonbenzoic acid; Structure

Community：

[ 1 ] [Sun, Y.-Q.]College of Chemistry, Fuzhou University, Fuzhou, 350002, China
[ 2 ] [Sun, Y.-Q.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China
[ 3 ] [Zhong, J.-C.]College of Chemistry, Fuzhou University, Fuzhou, 350002, China
[ 4 ] [Liu, L.-H.]College of Chemistry, Fuzhou University, Fuzhou, 350002, China
[ 5 ] [Qiu, X.-T.]College of Chemistry, Fuzhou University, Fuzhou, 350002, China
[ 6 ] [Chen, Y.-P.]College of Chemistry, Fuzhou University, Fuzhou, 350002, China

Reprint 's Address：

[Sun, Y.-Q.]College of Chemistry, Fuzhou UniversityChina

Email：

sunyq@fzu.edu.cn

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Source ：

Journal of Molecular Structure

ISSN： 0022-2860

Year： 2016

Volume： 1124

Page： 138-143

1 . 7 5 3

JCR@2016

4 . 0 0 0

JCR@2023

ESI HC Threshold：235

JCR Journal Grade：3

CAS Journal Grade：4

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WoS CC Cited Count：

SCOPUS Cited Count： 7

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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