Construction of High-Nuclearity Manganese-Cluster-Organic Frameworks by Using a Tripodal Alcohol Ligand - Details

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Abstract：

Two　novel　cluster-organic　frameworks　based　on　the　12-nuclearity　manganese-cluster　secondary　building　unit　(SBU),　[MnIII　4MnII　8(L)4(Ac)8(MeO)2(μ5-O)2(H2O)4](Ac)2·16H2O　(1)　and　[MnIII　4MnII　8(L)4(Ac)8(MeO)2(μ5-O)2(H2O)4](Ac)2·12H2O　(2),　where　Ac　=　CH3COO-　and　MeO　=　CH3O,　have　been　constructed　from　solvothermal　reactions　of　the　3-nuclearity　manganese　cluster　[Mn3(μ3-O)(Ac)6(py)3](ClO4)　(Mn3,　where　py　=　pyridine)　with　a　tripodal　alcohol　ligand　containing　a　4-pyridyl　group.　1　and　2　represent　the　first　examples　of　metal-organic　frameworks　containing　12-nuclearity　manganese-cluster　SBUs.　In　addition,　1　exhibits　an　integration　of　the　porosity　and　magnetic　properties　from　both　the　framework　and　cluster　in　a　porous　material.　©　2016　American　Chemical　Society.

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[ 1 ] [Ma, X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 2 ] [Zhao, D.]Fuqing Branch of Fujian Normal University, Fuqing, Fujian, 350300, China
[ 3 ] [Lin, L.-F.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 4 ] [Qin, S.-J.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 5 ] [Zheng, W.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 6 ] [Qi, Y.-J.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 7 ] [Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 8 ] [Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China

Reprint 's Address：

[Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

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lxx@fzu.edu.cn

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Inorganic Chemistry

ISSN： 0020-1669

Year： 2016

Issue： 21

Volume： 55

Page： 11311-11315

4 . 8 5 7

JCR@2016

4 . 3 0 0

JCR@2023

ESI HC Threshold：235

JCR Journal Grade：1

CAS Journal Grade：1

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SCOPUS Cited Count： 23

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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