Composite Hybrid Cluster Built from the Integration of Polyoxometalate and a Metal Halide Cluster: Synthetic Strategy, Structure, and Properties - Details

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Abstract：

A　step-by-step　synthetic　strategy,　setting　up　a　bridge　between　the　polyoxometalate　(POM)　and　metal　halide　cluster　(MHC)　systems,　is　demonstrated　to　construct　an　unprecedented　composite　hybrid　cluster　built　up　from　one　high-nuclearity　cationic　MHC　[Cu8I6]2+　and　eight　Anderson-type　anionic　POMs　[HCrMo6O18(OH)6]2-　cross-linked　by　a　tripodal　alcohol　derivative.　©　2016　American　Chemical　Society.

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[ 1 ] [Li, X.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 2 ] [Ma, X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 3 ] [Zheng, W.-X.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 4 ] [Qi, Y.-J.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 5 ] [Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, Fujian, 350108, China
[ 6 ] [Yang, G.-Y.]MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing, 100081, China

Reprint 's Address：

[Zheng, S.-T.]State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou UniversityChina

Email：

stzheng@fzu.edu.cn

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Source ：

Inorganic Chemistry

ISSN： 0020-1669

Year： 2016

Issue： 17

Volume： 55

Page： 8257-8259

4 . 8 5 7

JCR@2016

4 . 3 0 0

JCR@2023

ESI HC Threshold：235

JCR Journal Grade：1

CAS Journal Grade：1

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SCOPUS Cited Count： 49

ESI Highly Cited Papers on the List： 0 Unfold All

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Chinese Cited Count：

30 Days PV： 1

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