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author:

Zhou, L. (Zhou, L..) [1] | Niu, Y. (Niu, Y..) [2] | Yang, J. (Yang, J..) [3] | Li, C. (Li, C..) [4] | Guo, X. (Guo, X..) [5] | Li, L. (Li, L..) [6] | Qiu, T. (Qiu, T..) [7]

Indexed by:

Scopus

Abstract:

Sulfated titania (SO4 2−/TiO2) was prepared and characterized by nitrogen adsorption-desorption, FT-IR, thermostability analyzer, XRD and particle size analyzer. The esterification of myristic acid (MA) with isopropanol (IPOH) catalyzed by the solid super acid SO4 2−/TiO2 was studied. The effect of reaction kinetics conditions such as temperature, stirrer speed, initial mole ratio of alcohol to acid, and catalyst loading on the conversion of myristic acid was investigated. A second-order pseudo-homogeneous model was developed to calculate the rate of the reaction, and then the kinetic parameters were estimated. The calculated values were in agreement with experimental data. © 2016, Korean Institute of Chemical Engineers, Seoul, Korea.

Keyword:

Esterification; Isopropyl Myristate; Kinetics; SO4 2−/TiO2

Community:

  • [ 1 ] [Zhou, L.]School of Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350116, China
  • [ 2 ] [Niu, Y.]School of Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350116, China
  • [ 3 ] [Yang, J.]School of Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350116, China
  • [ 4 ] [Yang, J.]School of Ocean Science and Biochemistry Engineering, Fuqing Branch of Fujian Normal University, Fuzhou, Fujian, 350300, China
  • [ 5 ] [Li, C.]School of Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350116, China
  • [ 6 ] [Guo, X.]School of Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350116, China
  • [ 7 ] [Li, L.]School of Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350116, China
  • [ 8 ] [Qiu, T.]School of Chemical Engineering, Fuzhou University, Fuzhou, Fujian, 350116, China

Reprint 's Address:

  • [Qiu, T.]School of Chemical Engineering, Fuzhou UniversityChina

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Source :

Korean Journal of Chemical Engineering

ISSN: 0256-1115

Year: 2016

Issue: 8

Volume: 33

Page: 2478-2485

2 . 0 0 7

JCR@2016

3 . 0 0 0

JCR@2023

ESI HC Threshold:235

JCR Journal Grade:2

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 7

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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